How to Grow Copper Acetate Monohydrate Crystals

Its easy to grow blue-green monoclinic crystals of copper acetate monohydrate [Cu(CH3COO)2.H2O]. Difficulty: Easy Time Required: a few days What You Need To Grow Copper Acetate Crystals copper acetate monohydratehot distilled wateracetic acid (if necessary) How To Grow Copper Acetate Crystals Dissolve 20 grams of copper acetate monohydrate in 200 ml of hot distilled water.If there is a scum of undissolved material, stir in a couple of drops of acetic acid.Cover the solution with a paper towel or coffer filter and allow it to cool in an undisturbed location.Blue-green crystals should start to spontaneously deposit within a couple of days. You can allow them to grow or can select one small crystal to use as a seed crystal to grow a larger single crystal.

What Was Freedom For African Americans - 961 Words

In 1865, slavery was abolished, by the Thirteenth amendment. This Amendment brought humongous changes and a large number of problems. (Lecture 1) After the destruction of slavery, it left nearly four million African American with no property, little training, and few rights; which made the definition of freedom for African Americans the central question on the nation’s agenda. The big question of the time period was, â€Å"what was freedom for African Americans?† (Give me liberty! An American 550) From 1865 to 1900 African Americans, despite being presumed free; blacks quickly realized they were only free from was the whippings, break-ups from their families, and sexual exploitation. (Experience History 457) African Americans were still force to live with the hostility of whites. It has taken blacks a long time to be freed from the hatred, and discrimination of white southerners, and after decades’ racism among whites still exist today. For African Americans discovering their own meaning of freedom was crucial. Establishing the meaning of free included finding a new place to work. In attempt to break the psychological ties of slavery, the changing of jobs was necessary. Possessing a full name, including a last name, that they were allowed to choose. This marked the first sign that slaves had the freedom to make a decision without white interference. Pursuing the opportunity to strengthen their family ties, meaning getting officially married because slave marriages had neverShow MoreRelatedThe Importance of the Civil Rights Leaders Essay1391 Words   |  6 Pagestheir lives and their freedom. Civil right leaders fought for equality and freedom for African Americans. Over 70% of African Americans were experiencing segregation and discrimination during the civil right movement. African Americans only had one another for support, so during this time African Americans appreciated civil right leaders. During the civil ri ghts movement, many leaders helped African Americans cope with changes that they were experiencing. Some African Americans looked up to civil rightsRead MoreAfrican Americans During The Revolutionary Era925 Words   |  4 PagesRevolutionary Era was a time for liberal reformation, independence, and a new found united states. An uprising for freedom from Britain’s tyrannic king swept through the colonies and a fight for independence was making it’s way. However, the war with Britain would be no cake walk for the new found colonies and extra reinforcement was needed. African Americans played major roles during the Revolutionary Era by participating in battles such as Lexington, Bunker Hill, and Yorktown. Some were free African AmericansRead MoreThe Reconstruction Era Was A Time For America To Heal,1375 Words   |  6 PagesThe Reconstruction Era was a time for America to heal, a time to recuperate and move forward, but certain things take longer than others. One issue that took tremendous effort was the advancement of African-Americans. Freedman were freed by law, but still mentally, socioeconomically, and socially bonded to oppression. Even after the Civil War ended, the fight wasn’t over; there was a war within the government itself, and a greater fight for freedman to achieve economic freedom without barriers. AsRead MoreBlack Codes, Redemption, And Jim Crow1042 Words   |  5 Pages† Healing to African Americans meant trying to understand their role as a citizen, reuniting family members, and establishing their new freedoms as citizens. Many problems interfered with this process. Black codes, Redemption, and Jim Crow are all examples of initial offering and then revoking of freedoms toward African Americans throughout Reconstruction. African Americans did not lose without a fight though; some even maintained it. Blacks resisted their revocation of their freedom through the developmentRead MoreNative American And Native Americans 950 Words   |  4 Pagesthrough imperialism, reconstruction and wars to pursuit their freedom. Native American’s embarked on new discoveries in America, which began conflicts with White Americans wanting control over what Native American had. Native Americans believed in freedom for the nation, but things began to change for them, when White American passed the Indians removal act. African American and Native American had similar experiences to pursuit their freedom. Both races were treated like they didn’t exist in the world;Read MoreFrederick Douglass : African American Freedom Struggle888 Words   |  4 PagesFrederick Douglass became a vital figure for the African American freedom struggle during the 1860’s with the help of the abolitionist movement. 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Free or enslaved, African-American were underRead MoreThe Negative Effects Of Slavery On African Americans839 Words   |  4 PagesSlavery was a sad event that African Americans had to go through in America starting in the sixteen hundredths. Slavery was bad because African Americans were kidnapped from Af rica by Slave Traders and put on slave ships that enslaved African Americans. The Atlantic Slave Trade is the transportation by slave traders of enslaved African people. Mainly from Africa to America and then, Africans were sold into slavery. Innocent African Americans were captured and beaten almost to death in captivity byRead MoreThe Freedom And Freedom Of The United States1499 Words   |  6 PagesKnowing the Meaning of Freedom Freedom and liberties are the most popular and significant topic in the United States. However, what’s the freedom and who can enjoy the freedom became the controversial arguments in America during its post-civil war period. Since people with different gender, different race, and even different customs may have their own opinions and prospects of the rights they should have, white Americans, African Americans, immigrants and even women were trying to define and striveRead MoreThe Freedom Riders For African Americans1491 Words   |  6 PagesWho are the Freedom Riders you may ask? They were a courageous and daring group, which originally consisted of seven African Americans and six Whites.They fought for the equality and justice for their race. They fought against the racist South during the early 1960’s. Their goal was to make a safer and more fair world for current and future African Americans in the United States. They went through hardship and violence from things s uch as, angry mobs and racist law enforcement through a period of

Antoine-Laurent de Lavoisier Free Essays

string(44) " a treatise upon the Elements of Chemistry\." Daniel Rutherford Jacobus Henricus Walther Hermann Nernst Reinhold Benesch Ruth Erica Benesch Find How Oxygen is Transported in Human Body Frederick Soddy Artturi Ilmari Virtanen Louis Jacques Thenard discovers hydrogen peroxide Jbir ibn Hayyn Ya’qub Al-Kindi Paul Karrer Antoine-Laurent de Lavoisier Few things are as important as water, which we know is made of oxygen and hydrogen. Did you know that Antoine Lavoisier was the discoverer of both elements? Contributions to Science Antoine-Laurent de Lavoisier is one of the most important scientists in the history of chemistry. He discovered elements, formulated a basic law of chemistry and helped create the metric system. We will write a custom essay sample on Antoine-Laurent de Lavoisier or any similar topic only for you Order Now During his time, people believed that when an object burns, a mysterious substance called ‘phlogiston’ was released. This was called the ‘phlogiston theory’. Lavoisier’s experiments demonstrated the contrary, i. e. when something burned, it actually absorbed something from the air, instead of releasing anything. He later named the ‘something’ from the air as oxygen, when he found that it combined with other chemicals to form acid. (In Greek, ‘oxy’ means sharp, referring to the sharp taste of acids. Henry Cavendish had earlier isolated hydrogen, but he called it inflammable air. Lavoisier showed that this inflammable air burned to form a colourless liquid, which turned out to be water. The Greek word for water is ‘hydro’, so the air that burned to form water was hydrogen! Lavoisier was known for his painstaking attention to detail. Whenever he made a chemical reaction, he weighed all the substances carefully befo re and after the reaction. He discovered that in a chemical reaction, though substances may change their chemical nature, their total mass remains the same. This is called the law of conservation of mass. His love for accuracy led to the formulation of the metric system of weights and measures – which is still in use today. Lavoisier’s attention to detail and habit of recording everything is perhaps his most important contribution – for that is now the way science is done. Biography Lavoiser was born on 26 August 1743 in a wealthy Parisian family. He studied at the College Mazarin from 1754 to 1761. His interest in chemistry was developed as he read the works of Etienne Condillac. In 1769, he set about making a geological map of France, which was important for that country’s industrial development. In 1769, he took a government position as a tax collector in the government of King Louis XVI. In 1771, he married Marie-Anne Pierette Paulze, who is considered as an eminent scientist in her own right. She translated the works of many scientists from English and German into French, and later on, with her husband, published the Traite elementaire de chimie, often considered the first comprehensive book on the subject. In 1789, King Louis XVI was overthrown in the French Revolution. As Lavoisier had been a tax collector, he earned the wrath of the revolutionaries, who executed him on 8 May 1794. SOURCE: http://humantouchofchemistry. com/antoinelaurent-de-lavoisier. htm Elements and Atoms: Chapter 3 Lavoisier’s Elements of Chemistry Antoine-Laurent Lavoisier (1743-1794) has been called the founder of modern chemistry. (View a portrait of Mme. M. Lavoisier by Jacque-Louis David at the Metropolitan Museum of Art, New York. Among his important contributions were the application of the balance and the principle of conservation of mass to chemistry, the explanation of combustion and respiration in terms of combination with oxygen rather than loss of phlogiston (See chapter 5. ), and a reform of chemical nomenclature. His Traite Elementaire de Chimie (1789), from which the present extract is taken in a contemporary translation, was a tremendously influential synthesis of his work. Lavoisier was a public servant as well as a scientist. Under the French monarchy, he was a member of the tax-collecting agency, the Ferme Generale. His work for the government included advocating rational agricultural methods and improving the manufacture of gunpowder. His service to France continued during the Revolution. He was an alternate deputy of the reconvened Estates-General in 1789, and from 1790 served on a commission charged with making weights and measures uniform across France. A Parisian by birth, Lavoisier also died in Paris, guillotined with other former members of the Ferme Generale during the Reign of Terror in May 1794. The preface to his Traite Elementaire de Chimie is a fitting selection to follow Boyle’s The Sceptical Chymist because it includes the definition of element that was to dominate chemistry throughout the next century, and which is still familiar in our own day. In addition, Lavoisier’s musings on the connection between science and the language which conveys its ideas remain thought-provoking, particularly in light of the writings of Bertrand Russell, Ludwig Wittgenstein, and Alfred Ayer in the first half of the 20th century. Even his comments about the pedagogy of introductory chemistry take sides in a debate that remains current. Antoine Lavoisier, Preface to Elements of Chemistry translation by Robert Kerr (Edinburgh, 1790), pp. xiii-xxxvii When I began the following Work, my only object was to extend and explain more fully the Memoir which I read at the public meeting of the Academy of Science in the month of April 1787, on the necessity of reforming and completing the Nomenclature of Chemistry[1]. While engaged in this employment, I perceived, better than I had ever done before, the justice of the following maxims of the Abbe de Condillac[2], in his System of Logic, and some other of his works. â€Å"We think only through the medium of words. –Languages are true analytical methods. –Algebra, which is adapted to its purpose in every species of expression, in the most simple, most exact, and best manner possible, is at the same time a language and an analytical method. –The art of reasoning is nothing more than a language well arranged. † Thus, while I thought myself employed only in forming a Nomenclature, and while I roposed to myself nothing more than to improve the chemical language, my work transformed itself by degrees, without my being able to prevent it, into a treatise upon the Elements of Chemistry. You read "Antoine-Laurent de Lavoisier" in category "Essay examples" The impossibility of separating the nomenclature of a science from the scie nce itself, is owing to this, that every branch of physical science must consist of three things; the series of facts which are the objects of the science, the ideas which represent these facts, and the words by which these ideas are expressed. Like three impressions of the same seal, the word ought to produce the idea, and the idea to be a picture of the fact. And, as ideas are preserved and communicated by means of words, it necessarily follows that we cannot improve the language of any science without at the same time improving the science itself; neither can we, on the other hand, improve a science, without improving the language or nomenclature which belongs to it. However certain the facts of any science may be, and, however just the ideas we may have formed of these facts, we can only communicate false impressions to others, while we want words by which these may be properly expressed. 3] To those who will consider it with attention, the first part of this treatise will afford frequent proofs of the truth of the above observations. But as, in the conduct of my work, I have been obliged to observe an order of arrangement essentially differing from what has been adopted in any other chemical work yet published, it is proper that I should explain the motives which have led me to do so. It is a maxim universally admitted in geometry, and indeed in every branch of knowledge, that, in the progress of investigation, we should proceed from known facts to what is unknown. In early infancy, our ideas spring from our wants; the sensation of want excites the idea of the object by which it is to be gratified. In this manner, from a series of sensations, observations, and analyses, a successive train of ideas arises, so linked together, that an attentive observer may trace back to a certain point the order and connection of the whole sum of human knowledge. When we begin the study of any science, we are in a situation, respecting that science, similar to that of children; and the course by which we have to advance is precisely the same which Nature follows in the formation of their ideas. In a child, the idea is merely an effect produced by a sensation; and, in the same manner, in commencing the study of a physical science, we ought to form no idea but what is a necessary consequence, and immediate effect, of an experiment or observation. [4] Besides, he that enters upon the career of science, is in a less advantageous situation than a child who is acquiring his first ideas. To the child, Nature gives various means of rectifying any mistakes he may commit respecting the salutary or hurtful qualities of the objects which surround him. On every occasion his judgments are corrected by experience; want and pain are the necessary consequences arising from false judgment; gratification and pleasure are produced by judging aright. Under such masters, we cannot fail to become well informed; and we soon learn to reason justly, when want and pain are the necessary consequences of a contrary conduct. [5] In the study and practice of the sciences it is quite different; the false judgments we form neither affect our existence nor our welfare; and we are not forced by any physical necessity to correct them. Imagination, on the contrary, which is ever wandering beyond the bounds of truth, joined to self-love and that self-confidence we are so apt to indulge, prompt us to draw conclusions which are not immediately derived from facts; so that we become in some measure interested in deceiving ourselves. Hence it is by no means to be wondered, that, in the science of physics in general, men have often made suppositions, instead of forming conclusions. These suppositions, handed down from one age to another, acquire additional weight from the authorities by which they are supported, till at last they are received, even by men of genius, as fundamental truths. The only method of preventing such errors from taking place, and of correcting them when formed, is to restrain and simplify our reasoning as much as possible. This depends entirely upon ourselves, and the neglect of it is the only source of our mistakes. We must trust to nothing but facts: These are presented to us by Nature, and cannot deceive. We ought, in every instance, to submit our reasoning to the test of experiment, and never to search for truth but by the natural road of experiment and observation. Thus mathematicians obtain the solution of a problem by the mere arrangement of data, and by reducing their reasoning to such simple steps, to conclusions so very obvious, as never to lose sight of the evidence which guides them. [6] Thoroughly convinced of these truths, I have imposed upon myself, as a law, never to advance but from what is known to what is unknown; never to form any conclusion which is not an immediate consequence necessarily lowing from observation and experiment; and always to arrange the fact, and the conclusions which are drawn from them, in such an order as shall render it most easy for beginners in the study of chemistry thoroughly to understand them. Hence I have been obliged to depart from the usual order of courses of lectures and of treatises upon chemistry, which always assume the first princ iples of the science, as known, when the pupil or the reader should never be supposed to know them till they have been explained in subsequent lessons. In almost every instance, these begin by treating of the elements of matter, and by explaining the table of affinities[7], without considering, that, in so doing, they must bring the principal phenomena of chemistry into view at the very outset: They make use of terms which have not been defined, and suppose the science to be understood by the very persons they are only beginning to teach. 8] It ought likewise to be considered, that very little of chemistry can be learned in a first course, which is hardly sufficient to make the language of the science familiar to the ears, or the apparatus familiar to the eyes. It is almost impossible to become a chemist in less than three or four years of constant application. These inconveniencies are occasioned not so much by the nature of the subject, as by the method of teaching it; and, to avoid them, I was chiefly induced to adopt a new arrangement of chemistry, which appeared to me more consonant to the order of Nature. I acknowledge, however, that in thus endeavouring to avoid difficulties of one kind, I have found myself involved in others of a different species, some of which I have not been able to remove; but I am persuaded, that such as remain do not arise from the nature of the order I have adopted, but are rather consequences of the imperfection under which chemistry still labours. This science still has many chasms, which interrupt the series of facts, and often render it extremely difficult to reconcile them with each other: It has not, like the elements of geometry, the advantage of being a complete science, the parts of which are all closely connected together: Its actual progress, however, is so rapid, and the facts, under the modern doctrine, have assumed so happy an arrangement, that we have ground to hope, even in our own times, to see it approach near to the highest state of perfection of which it is susceptible. 9] The rigorous law from which I have never deviated, of forming no conclusions which are not fully warranted by experiment, and of never supplying the absence of facts, has prevented me from comprehending in this work the branch of chemistry which treats of affinities, although it is perhaps the best calculated of any part of chemistry for being reduced into a completely systematic body. Messrs Geoffroy, Gellert, Bergman, Scheele, De Morveau, Kirwan,[10] and many others, have collected a number of particular facts upon this subject, which only wait for a proper arrangement; but the principal data are still wanting, or, at least, those we have are either not sufficiently defined, or not sufficiently proved, to become the foundation upon which to build so very important a branch of chemistry. This science of affinities, or elective attractions, holds the same place with regard to the other branches of chemistry, as the higher or transcendental geometry does with respect to the simpler and elementary part; and I thought it improper to involve those simple and plain elements, which I flatter myself the greatest part of my readers will easily understand, in the obscurities and difficulties which still attend that other very useful and necessary branch of chemical science. Perhaps a sentiment of self-love may, without my perceiving it, have given additional force to these reflections. Mr de Morveau is at present engaged in publishing the article Affinity in the Methodical Encyclopedia; and I had more reasons than one to decline entering upon a work in which he is employed. It will, no doubt, be a matter of surprise, that in a treatise upon the elements of chemistry, there should be no chapter on the constituent and elementary parts of matter; but I shall take occasion, in this place, to remark, that the fondness for reducing all the bodies in nature to three or four elements, proceeds from a prejudice which has descended to us from the Greek Philosophers. The notion of four elements, which, by the variety of their proportions, compose all the known substances in nature, is a mere hypothesis, assumed long before the first principles of experimental philosophy or of chemistry had any existence. In those days, without possessing facts, they framed systems; while we, who have collected facts, seem determined to reject them, when they do not agree with our prejudices. The authority of these fathers of human philosophy still carry great weight, and there is reason to fear that it will even bear hard upon generations yet to come. [11] It is very remarkable, that, notwithstanding of the number of philosophical chemists who have supported the doctrine of the four elements, there is not one who has not been led by the evidence of facts to admit a greater number of elements into their theory. The first chemists that wrote after the revival of letters, considered sulphur and salt as elementary substances entering into the composition of a great number of substances; hence, instead of four, they admitted the existence of six elements. Beccher assumes the existence of three kinds of earth, from the combination of which, in different proportions, he supposed all the varieties of metallic substances to be produced. Stahl gave a new modification to this system; and succeeding chemists have taken the liberty to make or to imagine changes and additions of a similar nature. All these chemists were carried along by the influence of the genius of the age in which they lived, which contented itself with assertions without proofs; or, at least, often admitted as proofs the slightest degrees of probability, unsupported by that strictly rigorous analysis required by modern philosophy. [12] All that can be said upon the number and nature of elements is, in my opinion, confined to discussions entirely of a metaphysical nature. The subject only furnishes us with indefinite problems, which may be solved in a thousand different ways, not one of which, in all probability, is consistent with nature. I shall therefore only add upon this subject, that if, by the term elements, we mean to express those simple and indivisible atoms of which matter is composed, it is extremely probable we know nothing at all about them; but, if we apply the term elements, or principles of bodies, to express our idea of the last point which analysis is capable of reaching, we must admit, as elements, all the substances into which we are capable, by any means, to reduce bodies by decomposition. 13] Not that we are entitled to affirm, that these substances we consider as simple may not be compounded of two, or even of a greater number of principles; but, since these principles cannot be separated, or rather since we have not hitherto discovered the means of separating them, they act with regard to us as simple substances, and we ought never to suppose them compounded until experiment and observation has proved them to be so. 14] The foregoing reflections upon the progress of chemical ideas naturally app ly to the words by which these ideas are to be expressed. Guided by the work which, in the year 1787, Messrs de Morveau, Berthollet, de Fourcroy, and I composed upon the Nomenclature of Chemistry, I have endeavoured, as much as possible, to denominate simple bodies by simple terms, and I was naturally led to name these first. 15] It will be recollected, that we were obliged to retain that name of any substance by which it had been long known in the world, and that in two cases only we took the liberty of making alterations; first, in the case of those which were but newly discovered, and had not yet obtained names, or at least which had been known but for a short time, and the names of which had not yet received the sanction of the public; and, secondly, when the names which had been adopted, whether by the ancients or the moderns, appeared to us to express evidently false ideas, when they confounded the substances, to which they were applied, with others possessed of different, or perhaps opposite qualities. We made no scruple, in this case, of substituting other names in their room, and the greatest number of these were borrowed from the Greek language. We endeavoured to frame them in such a manner as to express the most general and the most characteristic quality of the substances; and this was attended with the additional advantage both of assisting the memory of beginners, who find it difficult to remember a new word which has no meaning, and of accustoming them early to admit no word without connecting with it some determinate idea. 16] To those bodies which are formed by the union of several simple substances we gave new names, compounded in such a manner as the nature of the substances directed; but, as the number of double combinations is already very considerable, the only method by which we could avoid confusion, was to divide them into classes. In the natural order of ideas, the name of the class or genus is that which expresses a quality common to a great number of individuals: The name of the species, on the contrary, expresses a quality peculiar to certain individuals only. [17] These distinctions are not, as some may imagine, merely metaphysical, but are established by Nature. A child,† says the Abbe de Condillac, â€Å"is taught to give the name tree to the first one which is pointed out to him. The next one he sees presents the same idea, and he gives it the same name. This he does likewise to a third and a fourth, till at last the word tree, which he first applied to an individual, comes to be employed by him as the name of a class or a genus, an abstract idea, which comprehends all trees in general. But, when he learns that all trees serve not the same purpose, that they do not all produce the same kind of fruit, he will soon learn to distinguish them by specific and particular names. † This is the logic of all the sciences, and is naturally applied of chemistry. The acids, for example, are compounded of two substances, of the order of those which we consider as simple; the one constitutes acidity, and is common to all acids, and, from this substance, the name of the class or the genus ought to be taken; the other is peculiar to each acid, and distinguishes it from the rest, and from this substance is to be taken the name of the species. But, in the greatest number of acids, the two constituent elements, the acidifying principle, and that which it acidifies, may exist in different proportions, constituting all the possible points of equilibrium or of saturation. This is the case in the sulphuric and the sulphurous acids; and these two states of the same acid we have marked by varying the termination of the specific name. Metallic substances which have been exposed to the joint action of the air and of fire, lose their metallic lustre, increase in weight, and assume an earthy appearance. In this state, like the acids, they are compounded of a principle which is common to all, and one which is peculiar to each. In the same way, therefore, we have thought proper to class them under a generic name, derived from the common principle; for which purpose, we adopted the term oxyd; and we distinguish them from each other by the particular name of the metal to which each belongs. [18] Combustible substances, which in acids and metallic oxyds are a specific and particular principle, are capable of becoming, in their turn, common principles of a great number of substances. The sulphurous combinations have been long the only known ones in this kind. Now, however, we know, from the experiments of Messrs Vandermonde, Monge, and Berthollet, that charcoal may be combined with iron, and perhaps with several other metals; and that, from this combination, according to the proportions, may be produced steel, plumbago, c. [19] We know likewise, from the experiments of M. Pelletier, that phosphorus may be combined with a great number of metallic substances. These different combinations we have classed under generic names taken from the common substance, with a termination which marks this analogy, specifying them by another name taken from that substance which is proper to each. The nomenclature of bodies compounded of three simple substances was attended with still greater difficulty, not only on account of their number, but, particularly, because we cannot express the nature of their constituent principles without employing more compound names. In the bodies which form this class, such as the neutral salts, for instance, we had to consider, 1st, The acidifying principle, which is common to them all; 2d, The acidifiable principle which constitutes their peculiar acid; 3d, The saline, earthy, or metallic basis, which determines the particular species of salt. Here we derived the name of each class of salts from the name of the acidifiable principle common to all the individuals of that class; and distinguished each species by the name of the saline, earthy, or metallic basis, which is peculiar to it. [20] A salt, though compounded of the same three principles, may, nevertheless, by the mere difference of their proportion, be in three different states. The nomenclature we have adopted would have been defective, had it not expressed these different states; and this we attained chiefly by changes of termination uniformly applied to the same state of the different salts. In short, we have advanced so far, that from the name alone may be instantly found what the combustible substance is which enters into any combination; whether that combustible substance be combined with the acidifying principle, and in what proportion; what is the state of the acid; with what basis it is united; whether the saturation be exact, or whether the acid or the basis be in excess. It may be easily supposed that it was not possible to attain all these different objects without departing, in some instances, from established custom, and adopting terms which at first sight will appear uncouth and barbarous. But we considered that the ear is soon habituated to new words, especially when they are connected with a general and rational system. The names, besides, which were formerly employed, such as powder of algaroth, salt of alembroth, pompholix, phagadenic water, turbith mineral, colcothar, and many others, were neither less barbarous nor less uncommon. [21] It required a great deal of practice, and no small degree of memory, to recollect the substances to which they were applied, much more to recollect the genus of combination to which they belonged. The names of oil of tartar per deliquium, oil of vitriol, butter of arsenic and of antimony, flowers of zinc, c. ere still more improper, because they suggested false ideas: For, in the whole mineral kingdom, and particularly in the metallic class, there exists no such thing as butters, oils, or flowers; and, in short, the substances to which they give these fallacious names, are nothing less than rank poisons. [22] When we published our e ssay on the nomenclature of chemistry, we were reproached for having changed the language which was spoken by our masters, which they distinguished by their authority, and handed down to us. But those who reproach us on this account, have forgotten that it was Bergman and Macquer themselves who urged us to make this reformation. In a letter which the learned Professor of Upsal, M. Bergman, wrote, a short time before he died, to M. de Morveau, he bids him spare no improper names; those who are learned, will always be learned, and those who are ignorant will thus learn sooner. 23] There is an objection to the work which I am going to present to the public, which is perhaps better founded, that I have given no account of the opinion of those who have gone before me; that I have stated only my own opinion, without examining that of others. By this I have been prevented from doing that justice to my associates, and more especially to foreign chemists, which I wished to render them. But I beseech the reader to consider, that, if I had filled an elementary work with a multitude of quotations; if I had allowed myself to enter into long dissertations on the history of the science, and the works of those who have studied it, I must have lost sight of the true object I had in view, and produced a work, the reading of which must have been extremely tiresome to beginners. It is not to the history of the science, or of the human mind, that we are to attend in an elementary treatise:[24] Our only aim ought to be ease and perspicuity, and with the utmost care to keep every thing out of view which might draw aside the attention of the student; it is a road which we should be continually rendering more smooth, and from which we should endeavour to remove every obstacle which can occasion delay. The sciences, from their own nature, present a sufficient number of difficulties, though we add not those which are foreign to them. But, besides this, chemists will easily perceive, that, in the fist part of my work, I make very little use of any experiments but those which were made by myself: If at any time I have adopted, without acknowledgment, the experiments or the opinions of M. Berthollet, M. Fourcroy, M. de la Place, M. Monge, or, in general, of any of those whose principles are the same with my own, it is owing to the circumstance, that frequent intercourse, and the habit of communicating our ideas, our observations, and our way of thinking to each other, has established between us a sort of community of opinions, in which it is often difficult for every one to know his own. [25] The remarks I have made on the order which I thought myself obliged to follow in the arrangement of proofs and ideas, are to be applied only to the first part of this work. It is the only one which contains the general sum of the doctrine I have adopted, and to which I wished to give a form completely elementary. 26] The second part is composed chiefly of tables of the nomenclature of the neutral salts. To these I have only added general explanations, the object of which was to point out the most simple processes for obtaining the different kinds of known acids. This part contains nothing which I can call my own, and prese nts only a very short abridgment of the results of these processes, extracted from the works of different authors. In the third part, I have given a description, in detail, of all the operations connected with modern chemistry. I have long thought that a work of this kind was much wanted, and I am convinced it will not be without use. The method of performing experiments, and particularly those of modern chemistry, is not so generally known as it ought to be; and had I, in the different memoirs which I have presented to the Academy, been more particular in the detail of the manipulations of my experiments, it is probable I should have made myself better understood, and the science might have made a more rapid progress. The order of the different matters contained in this third part appeared to me to be almost arbitrary; and the only one I have observed was to class together, in each of the chapters of which it is composed, those operations which are most connected with one another. I need hardly mention that this part could not be borrowed from any other work, and that, in the principal articles it contains, I could not derive assistance from any thing but the experiments which I have made myself. I shall conclude this preface by transcribing, literally, some observations of the Abbe de Condillac, which I think describe, with a good deal of truth, the state of chemistry at a period not far distant from our own. These observations were made on a different subject; but they will not, on this account, have less force, if the application of them be thought just. [27] â€Å"Instead of applying observation to the things we wished to know, we have chosen rather to imagine them. Advancing from one ill founded supposition to another, we have at last bewildered ourselves amidst a multitude of errors. These errors becoming prejudices, are, of course, adopted as principles, and we thus bewilder ourselves more and more. The method, too, by which we conduct our reasonings is as absurd; we abuse words which we do not understand, and call this the art of reasoning. When matters have been brought this length, when errors have been thus accumulated, there is but one remedy by which order can be restored to the faculty of thinking; this is, to forget all that we have learned, to trace back our ideas to their source, to follow the train in which they rise, and, as my Lord Bacon says, to frame the human understanding anew. â€Å"This remedy becomes the more difficult in proportion as we think ourselves more learned. Might it not be thought that works which treated of the sciences with the utmost perspicuity, with great precision and order, must be understood by every body? The fact is, those who have never studied any thing will understand them better than those who have studied a great deal, and especially those who have written a great deal. At the end of the fifth chapter, the Abbe de Condillac adds: â€Å"But, after all, the sciences have made progress, because philosophers have applied themselves with more attention to observe, and have commu nicated to their language that precision and accuracy which they have employed in their observations: In correcting their language they reason better. † Antoine Lavoisier, Table of Simple Substances in Elements of Chemistry translation by Robert Kerr (Edinburgh, 1790), pp. 175-6 Simple substances belonging to all the kingdoms of nature, which may be considered as the elements of bodies. New Names. | Correspondent old Names. | Light[28]| Light. | Caloric| Heat. | | Principle or element of heat. | | Fire. Igneous fluid. | Matter of fire and of heat. | Oxygen[29]| Depholgisticated air. | | Empyreal air. | | Vital air, or | | Base of vital air. | Azote[30]| Phlogisticated air or gas. | | Mephitis, or its base. | Hydrogen[31]| Inflammable air or gas, | | or the base of inflammable air. | Oxydable[32] and Acidifiable simple Substances not Metallic. New Names. | Correspondent old names. | Sulphur| The same names. | Phosphorus | | Charcoal | | Muriatic radical[33]| Still unknown. | Fl uoric radical | | Boracic radical| | Oxydable and Acidifiable simple Metallic Bodies. New Names. | Correspondent Old Names. | Antimony| Regulus[34] of| Antimony. | Arsenic| † â€Å"| Arsenic | Bismuth| † â€Å"| Bismuth | Cobalt| † â€Å"| Cobalt | Copper| † â€Å"| Copper | Gold| † â€Å"| Gold | Iron| † â€Å"| Iron | Lead| † â€Å"| Lead | Manganese| † â€Å"| Manganese | Mercury| † â€Å"| Mercury | Molybdena[35]| † â€Å"| Molybdena | Nickel| † â€Å"| Nickel | Platina| † â€Å"| Platina | Silver| † â€Å"| Silver | Tin| † â€Å"| Tin | Tungstein[36]| † â€Å"| Tungstein | Zinc| † â€Å"| Zinc| Salifiable simple Earthy Substances[37] New Names. | Correspondent Old Names. | Lime| Chalk, calcareous earth. | | Quicklime. | Magnesia| Magnesia, base of Epsom salt. | | Calcined or caustic magnesia. | Barytes| Barytes, or heavy earth. | Argill| Clay, earth of alum. | Silex| Siliceous or vitrifiable earth. | Notes [1]Lavoisier read â€Å"Methode de Nomenclature Chimique† before the French Academy on 18 April 1787. This outline for a reformulation of chemical nomenclature was prepared by Lavoisier and three of his early converts to the oxygen theory of combustion, Louis Bernard Guyton de Morveau, Claude Louis Berthollet, and Antoine Francois de Fourcroy. De Morveau had already argued for a reformed nomenclature, and he developed the April 1787 outline in a memoir read to the Academy on 2 May 1787. [Leicester Klickstein 1952] [2]Etienne Bonnot de Condillac (1715-1780) was a French philosopher and associate of Rousseau, Diderot, and the Encyclopedists. His La Logique (1780) stressed the importance of language as a tool in scientific and logical reasoning. [3]Lavoisier makes an excellent point, but he overstates it. Clearly ones ideas are not strictly limited or determined by one’s language. New ideas must exist before new terms can be coined to express those ideas; thus new ideas can be formed and even to some extent described under the sway of older language. Also, new terms can only be defined by reference to pre-existing terms. Sometimes new terms are not necessary, as old terms absorb new meanings. For example, I hope that the selections in this book show to some extent how the terms â€Å"atom† and â€Å"element† have changed in meaning over time. Having made these points, I do not wish to minimize the ability of new terminology to help the mind to run along the path of new insights, or to prevent it from falling into old misconceptions. [4]Note that Lavoisier does not say merely that we ought not believe any idea but what follows immediately and necessarily from experiment, we ought not even form the idea. This statement shows a wariness of hypotheses common to many early scientists and natural philosophers. Compare Newton’s, â€Å"I frame no hypotheses; for †¦ hypotheses †¦ have no place in experimental philosophy. † [in Bartlett 1980] Hypotheses had no part in the empirical methodology of Francis Bacon (1561-1626; see portrait at National Portrait Gallery, London), which emphasized collection and classification of facts. This aversion to hypotheses is too not urprising if one considers that empiricists were attempting to distance themselves from rationalism. Later formulations of the scientific metho d, however, acknowledge the utility of hypotheses, always treated as provisional, in both suggesting experiments and interpreting them. [5]Lavoisier was not the last to observe that children are born scientists who learn by experience. [6]Lavoisier’s choice of mathematics as an example may strike a modern reader as odd. While mathematics has long served as an example of the kind of certainty to which scientists aspire (â€Å"mathematical certainty†), it is now seen as based on axioms, not empirically based. Such mathematical systems as non-Euclidean geometry, which seemed to disagree with observed reality, had not yet been constructed at the time of Lavoisier’s writing, though. [7]A table of affinities was a summary of a great deal of information on chemical reactions. It lists what substances react chemically with a given substance, often in order of the vigor or extent of the reaction. (If substance A reacted more strongly than substance B with a given material, then substance A was said to have a greater affinity than B for that material. ) View a table of affinities by Etienne-Francois Geoffroy (1672-1731). [8]In Lavoisier’s mind, it makes no sense to jump to this summary table without first describing the various substances and their characteristic reactions. The proper role of descriptive chemistry in the chemical curriculum continues to be a topic of debate in chemical education. Apparently Lavoisier would be quite sympathetic to the charge that introductory courses emphasize unifying principles at the expense of descriptive chemistry. [9]This is certainly an optimistic statement! Two hundred years later chemistry has developed to an extent Lavoisier could not have imagined, yet it is a rare and foolish chemist who expects the science to exhaust its possibilities for discovery within a lifetime. [10]Bergman, Scheele, De Morveau, and Kirwan were all contemporaries of Lavoisier. The Swedish chemist Carl Wilhelm Scheele had a hand in the discovery of oxygen, chlorine, and manganese. The Swedish chemist and mineralogist Torbern Bergman made contributions to analytical chemistry and the classification of minerals. Richard Kirwan was an Irish chemist and a defender of the phlogiston theory. [11]The influence of the ancients was on the decline when Lavoisier wrote these words, but he does not exaggerate the importance of their thought. Remember that he is still concerned about their influence more than a century after The Sceptical Chymist and more than two millennia after the death of Aristotle. (See chapters 1 and 2. ) The simplicity of ancient ideas of matter would continue to have an influence on chemists well after Lavoisier’s time, particularly as the number of chemical elements grew. (See chapter 10. [12]Johann Joachim Becher (1635-1682) and Georg Ernst Stahl (1660-1734) were the two men most closely associated with the phlogiston theory. Lavoisier was largely responsible for dislodging and discrediting the notion that combustion and respiration involv ed a loss of a subtle material called phlogiston. (See chapter 5. ) Lavoisier makes light of their ideas here, but the theory, though incorrect, was not as nonsensical as it may now appear. [13]Notice the pragmatism of Lavoisier’s approach: he suggests, in essence, forgetting about the ultimate building blocks of matter. This was a prudent recommendation, for he had no way of addressing that subject empirically (which is why he dismisses it as metaphysical). He continues by suggesting that chemists turn their attention to what they can observe empirically, the ultimate products of chemical analysis. The definition of an element as a body which cannot be broken down further by chemical analysis is an operational one: as the techniques of chemical analysis improved, then substances scientists had any right to regard as elements could change. At first, this definition of element appears to be similar to that of Boyle. (See chapter 2, note 9. ) However, Boyle seemed not to consider elementary substances which were not components of all compound matter. [14]Lavoisier’s table of simple bodies, reproduced below the preface, follows this prescription approximately, but not exactly. See note 33 below. ) [15]See note 34 below on names of metals. [16]Thus, where possible the name of a chemical substance should not simply be an arbitrary word, but should give some information about the substance. This principle is particularly evident in the modern systematic nomenclature of organic compounds: the name enables one who knows the rules of nomenclature and some organic chemistry to draw the structural formula of a compound from its name. (See IUPAC 1979, 1993. ) The principle is also evident in the nomenclature of inorganic compounds [IUPAC 1971], the class of compounds Lavoisier’s nomenclature primarily addresses. It is least vident in modern names of the elements, many of which are named after important scientists (e. g. curium, mendelevium, rutherfordium) or places important to the discoverers (e. g. polonium). (See Ringnes 1989 for etymology of elements’ names. ) Ironically, Lavoisier coined the name for an element central to his contributions to chemistry, a name of Greek origin chosen to convey information about the element which turned out to be incorrect. The name â€Å"oxygen† means â€Å"acid former,† for Lavoisier believed that oxygen was a component of all acids. [17]Already we see t he close connection Lavoisier envisioned between the language of chemistry and the content of the science. The system of naming compounds depends on classifying those compounds. Compounds belonging to the same class would have similar names. The name would also reflect the chemical composition of the substance. [18]So the classes of compounds included acids, oxides, sulfides, and the like. To specify which acid, a particular name was added, e. g. nitrous acid. Different suffixes distinguished between similar particular names (such as sulfuric and sulfurous–the -ic suffix applying to the more highly oxidized form). [19]What Lavoisier has in mind is a class of materials now called carbides, inorganic compounds of a metal and carbon (â€Å"charcoal†). But the examples he gives are not carbides. Steel is an alloy (a mixture or solution of metals, and therefore not a chemical compound of definite proportions); in particular, steel is principally iron with some carbon and sometimes other metals (such as chromium or manganese). Although plumbago has been used to refer to a variety of lead-containing substances (as might be guessed from the root plumb-), it also (as here) refers to the substance now called graphite, the form of carbon commonly used for pencil â€Å"leads. † [20]Again in the case of salts we see the nomenclature embodying the principles of the chemical theory of the day. A salt was seen as a compound of an acid and a base, and an acid itself a compound of an acidifiable part and an acidifying part. The acidifying part, whatever its nature, was believed to be common to all acids; since it would not distinguish one salt from another, it does not appear in the name of the salt. The salts, then, carry the name of the acidifiable piece and the base with which it combines. [21]Pompholix was a crude (i. e. , not very pure) zinc oxide (ZnO), sometimes known by the more pleasant but hardly more informative name flowers of zinc. Phagadenic water was a corrosive liquid used to cleanse ulcers; phagadenic refers to a spreading or â€Å"eating† ulcer. Colcothar is a brownish-red mixture containing primarily ferric oxide (Fe2O3) with some calcium sulfate (CaSO4). [Oxford 1971] [22]Oil of vitriol is sulfuric acid, a viscous liquid. Butter of arsenic (arsenic trichloride) is an oily liquid; and butter of antimony (antimony trichloride) is a colorless deliquescent solid. In one sense, these names are informative, for they suggest the physical appearance of the substances they name; they are, however, also misleading in the sense Lavoisier points out. [23]Lavoisier recognizes that even the most rationally designed nomenclature would be useless if chemists chose not to use it. A language is one of the most visible signs of a people and culture; naturally, efforts to tamper with it can meet with disapproval. Thus Lavoisier pays at least nominal attention to aesthetic and cultural considerations, noting just above that the new terms sound no more â€Å"barbarous† than some technical terms then in existence. In a similar vein, he makes a concession to linguistic conservatism still further above, where he indicates that he does not propose to displace familiar names, at least for elements. And here he concedes that one ought not lightly to tamper with language, but that in doing so he is responding to a need and a demand. [24]Chemistry curricula in general devote little time to the history of the science, and that little usually consists of anecdotes scattered among other material. Discoverers of laws and elements may be mentioned; the pathways of discovery, however, let alone false steps on those pathways, almost never are. (See, however, Giunta 2001. In my opinion, the teaching of scientific process (as opposed to content) suffers as a result. The emphasis on current content to the exclusion of historical material, however, itself has a long history and such distinguished advocates as Lavoisier. [25]The standards for crediting others for their ideas, particularly when they are similar t o one’s own, were not as stringent in Lavoisier’s time as in our own. And yet Lavoisier was criticized even by contemporaries for failing to give what they believed to be sufficient credit. For instance, Joseph Priestley did not believe Lavoisier gave him sufficient credit for the discovery of â€Å"dephlogisticated air† (oxygen) when he described his own similar experiments [Conant 1957]. And Lavoisier’s failure to credit James Watt and Henry Cavendish for their insights into the compound nature of water were a part of the sometimes rancorous â€Å"water controversy† [Ihde 1964]. See chapters 4 and 6 for articles on these subjects. [26]The first part of the treatise deals with gases, caloric, and the combustion of elements, so it truly contains the work most closely associated with Lavoisier. [27]Indeed, these words, which advocate empirical observation over rationalism as the source of reliable knowledge, apply to any science. [28]Light and caloric are not found on modern tables of elements because they are even matter, let alone elements of material bodies. Although a wave theory of light had been proposed by this time (by Christiaan Huygens), Newton’s corpuscular (particle) theory was widely accepted until the 19th century. Similarly, until the 19th century, heat was widely believed to be a material, a fluid which flowed out of hot bodies and into cold ones (even though mechanical theories of heat with a Newtonian pedigree also existed at this time). See chapter 5, note 17 for a description of Lavoisier’s thinking about heat and fire. ) [29]As mentioned above, the name oxygen means â€Å"acid former,† for Lavoisier believed (incorrectly) that oxygen was a component of all acids. Oxygen was a relatively recently discovered substance, and it did not have a standard name. The various names used for it are descriptive, but clumsy. â€Å"Dephlogisticated air† is particularly objectionable, for it described oxygen in terms of the phlogistion theory, which Lavoisier was in the process discrediting. [30]The name azote and the current name nitrogen were both used in English from the time of Lavoisier into the 19th century. Azote means â€Å"lifeless,† for breathing nitrogen does not sustain life. [31]Hydrogen means â€Å"water former,† for water results from the burning of hydrogen. (See chapter 6. ) Hydrogen was one of several gases discovered in the 18th century. The names then in use for it were informative, denoting its flammability. [32]I. e. substances which can be oxidized (combined with oxygen). [33]These three radicals or â€Å"roots† had not yet been isolated or properly characterized. The fluoric radical, now called fluorine, is the root of fluorspar and other fluorine-containing minerals. Fluorine is very difficult to separate from its compounds, and is a very reactive and dangerous gas in its elemental form. This gas was not isolated until 1886. The boracic radical, now called boron, is the root of the mineral borax (Na2B4O7); boron was not isolated until 1808. [Weeks Leicester, 1968] Muriatic acid was the name then in use for what we call hydrochloric acid or hydrogen chloride, HCl. Chlorine, the element which distinguishes this acid from others, was discovered by Carl Wilhelm Scheele; however, he named it oxymuriatic acid, believing it to be a compound containing oxygen. Muriatic radical, then, was the name for the hypothetical element believed to be combined with oxygen in oxymuriatic acid. Muriatic, by the way, means â€Å"pertaining to †¦ brine or salt† [Oxford 1971]; the salt of muriatic acid is common table salt, sodium chloride (NaCl). Lavoisier had good reason to expect that these radicals would be isolated, for their compounds had been known for a long time; however, the fluoric and boracic radicals were, strictly speaking, hypothetical substances at this time, and the basis of muriatic acid had already been isolated but he did not recognize it as elementary. Had he kept strictly to the principle of considering a substance an element if it could not be further decomposed, then Lavoisier should also have included â€Å"oxymuriatic acid† (undoubtedly by a different name) among the elements; as it was, chlorine was named and recognized to be elementary only in 1810 [Davy 1810, 1811]. Although we can see, with hindsight, that Lavoisier was incorrect, it was by no means obvious at the time. Chlorine had been prepared from reactions with substances that do contain oxygen, for example from pyrolusite (MnO2) in Scheele’s original isolation and from aqueous muriatic acid (HCl). [34]Until the phlogiston theory was discarded, metals were commonly regarded as compounds of their minerals (â€Å"earths†) and phlogiston. This idea was incorrect, but it seemed to make sense, for the earths or ores seemed to be more fundamental than the metals. After all, the earths were found readily in nature, but to obtain the metals one had to heat the earths strongly in the presence of charcoal. In any event, the metal came to be known as the regulus of the mineral; for example, the name antimony was originally applied to an antimony sulfide, Sb2S3, and the metal was called regulus of antimony. Lavoisier drops the term regulus, giving the simple body (the metal) the simple, unmodified term. [35]The element is now known as molybdenum. Similarly Lavoisier’s platina is now called platinum. The ending is important: the -um ending now denotes a metal, while the -a ending denotes an oxide of that metal. [36]Now tungsten. [37]All of these â€Å"earthy substances† proved to be compounds. Their elements were first isolated in the early 19th century. Of course, Lavoisier was justified in including them among his elements, for none of them had yet been broken down into anything simpler. Two interesting omissions from this table are soda and potash, comounds of sodium and potassium known since antiquity but whose elementary metals had not yet been extracted. One might have expected Lavoisier to list such substances either here or with the hypothesized radicals (note 33). Chalk frequently refered to calcium carbonate (CaCO3), but apparently it was also used for calcium oxide [Oxford 1971]. Magnesia is magnesium oxide, MgO. (See note 35. Epsom salt is magnesium sulfate, MgSO4, so named for the location (an English town) of a mineral spring from which the salt was obtained. Barytes is barium oxide, BaO. Argill or argil is an aluminum-containing potters’ clay. Alum is a transparent aluminum-containing mineral, AlK(SO4)2. 12H2O. Humphry Davy was the first to isolate ca lcium, magnesium, barium, [Davy 1808b] sodium, and potassium [Davy 1808a]; he was also a co-discoverer of boron [Davy 1809] and he recognized chlorine to be an element (note 34). Vitrifiable means able to be made into glass; indeed, common glass is mainly silicon dioxide. [Weeks Leicester 1968] Source: http://web. lemoyne. edu/~giunta/ea/lavprefann. html Antoine-Laurent Lavoisier Antoine-Laurent Lavoisier. Line engraving by Louis Jean Desire Delaistre, after a design by Julien Leopold Boilly. Courtesy Blocker History of Medicine Collections, Moody Medical Library, University of Texas Medical Branch, Galveston, Texas. The son of a wealthy Parisian lawyer, Antoine-Laurent Lavoisier (1743–1794) completed a law degree in accordance with family wishes. His real interest, however, was in science, which he pursued with passion while leading a full public life. On the basis of his earliest scientific work, mostly in geology, he was elected in 1768—at the early age of 25—to the Academy of Sciences, France’s most elite scientific society. In the same year he bought into the Ferme Generale, the private corporation that collected taxes for the Crown on a profit-and-loss basis. A few years later he married the daughter of another tax farmer, Marie-Anne Pierrette Paulze, who was not quite 14 at the time. Madame Lavoisier prepared herself to be her husband’s scientific collaborator by learning English to translate the work of British chemists like Joseph Priestley and by studying art and engraving to illustrate Antoine-Laurent’s scientific experiments. In 1775 Lavoisier was appointed a commissioner of the Royal Gunpowder and Saltpeter Administration and took up residence in the Paris Arsenal. There he equipped a fine laboratory, which attracted young chemists from all over Europe to learn about the â€Å"Chemical Revolution† then in progress. He meanwhile succeeded in producing more and better gunpowder by increasing the supply and ensuring the purity of the constituents—saltpeter (potassium nitrate), sulfur, and charcoal—as well as by improving the methods of granulating the powder. Characteristic of Lavoisier’s chemistry was his systematic determination of the weights of reagents and products involved in chemical reactions, including the gaseous components, and his underlying belief that matter—identified by weight—would be conserved through any reaction (the law of conservation of mass). Among his contributions to chemistry associated with this method were the understanding of combustion and respiration as caused by chemical reactions with the part of the air (as discovered by Priestley) that he named â€Å"oxygen,† and his definitive proof by composition and decomposition that water is made up of oxygen and hydrogen. His giving new names to substances—most of which are still used today—was an important means of forwarding the Chemical Revolution, because these terms expressed the theory behind them. In the case of oxygen, from the Greek meaning â€Å"acid-former,† Lavoisier expressed his theory that oxygen was the acidifying principle. He considered 33 substances as elements—by his definition, substances that chemical analyses had failed to break down into simpler entities. Ironically, considering his opposition to phlogiston (see Priestley), among these substances was caloric, the unweighable substance of heat, and possibly light, that caused other substances to expand when it was added to them. To propagate his ideas, in 1789 he published a textbook, Traite Elementaire de chimie, and began a journal, Annales de Chimie, which carried research reports about the new chemistry almost exclusively. Antoine-Laurent Lavoisier conducts an experiment on human respiration in this drawing made by his wife, who depicted herself at the table on the far right. Courtesy Edgar Fahs Smith Memorial Collection, Department of Special Collections, University of Pennsylvania Library. A political and social liberal, Lavoisier took an active part in the events leading to the French Revolution, and in its early years he drew up plans and reports advocating many reforms, including the establishment of the metric system of weights and measures. Despite his eminence and his services to science and France, he came under attack as a former farmer-general of taxes and was guillotined in 1794. A noted mathematician, Joseph-Louis Lagrange, remarked of this event, â€Å"It took them only an instant to cut off that head, and a hundred years may not produce another like it. † Source: http://www. chemheritage. org/discover/online-resources/chemistry-in-history/themes/early-chemistry-and-gases/lavoisier. aspx Others: http://preparatorychemistry. com/Bishop_nomenclature_help. htm How to cite Antoine-Laurent de Lavoisier, Essay examples

A New Nation Essay Example For Students

A New Nation Essay A New Nation Begins?A City on a Hill?LipsetStarting things off, Lipset seems to be a very articulate man. His views on this beautiful country are exactly down to earth. Lipset began talking about how this country is the best in some areas but how we lack our supremacy in other areas. For instance I will express crime rate and military power. In Lipsets passage he stated that the crime rate in the United States is well above all other nations, but the American military is the strongest in the world. That is not a contradiction but only a mere example. Now with being the strongest military power in the world many smaller and third world countries tend to look up to us. That statement is easily represented by the fact that we are a ?city on a hill.? This nation might be on top is some aspects of the game but there is a few things that weigh us down. We won both world wars, set peace in the Middle East, and maintained our economic prowess. But are our greatest years starting to fall behind us? According to Lipset we are starting to distrust our leaders and have slim confidence in our institutions. That does not mean that everything is going south but what it really means is that we need to get in gear and do something about these situations. Not only are the Americans aware of this but so are other nations in the world. Japan knows our educational average is below standard. Germany knows that our some of our citizens hate our democracy. So once again the eyes of many are upon this huge city on top of a steep hill. Lipset then proceeded to talk about how a lot of our fine nations essays were written under the direction of ?foreign pens.? The only way that is possible is by comparing a culture that one is well established with to a culture that he is not that aware of. Most foreign travelers wrote about how exceptional this place is. Lipsets words say; exceptional is not that great. He defines exceptional as different and extraordinary. In all my years as a student most of my acquaintances like different or new things. Routine gets boring and most think change is only for the better. Living under the same rules and regulations that you been disagreeing with makes you jitty. You want to get up and do something about it. Maybe you could discover a new nation and start your own government. That is how our country was founded on or how the ?new nation began.?I am not trying to say that our country is not great in any means! Lipset said that we were one of the first ?new nations.? That is awesome! Ev erybody wants freedom and independence. Our country has those great virtues but we also have great morals set by the guy above. The United States does not make it mandatory for one to go to church but it emphasizes that it is for the better. The church as we know sets morals and standards into ones life. Mama America knows that church is a choice not a demand. Even if you sleep in on Sundays the guy above still sets the way of life. Creed is defined as ones passion for possession. Lipset said that America has creed that can be described in five terms. They are liberty, egalitarianism, individualism, populism, and laissez faire. He meant that this is the way America was formed not how everybody lives. America stresses on the people more than they stress on superiors. This is the best way. The more one can speak out against something they disagree with makes one feel good about all situations. Americans want control and dominance. While being on the top of the ?hill? us Americans must feel strong about things. .u80cd417e0d52d681b5bf737911f1be3d , .u80cd417e0d52d681b5bf737911f1be3d .postImageUrl , .u80cd417e0d52d681b5bf737911f1be3d .centered-text-area { min-height: 80px; position: relative; } .u80cd417e0d52d681b5bf737911f1be3d , .u80cd417e0d52d681b5bf737911f1be3d:hover , .u80cd417e0d52d681b5bf737911f1be3d:visited , .u80cd417e0d52d681b5bf737911f1be3d:active { border:0!important; } .u80cd417e0d52d681b5bf737911f1be3d .clearfix:after { content: ""; display: table; clear: both; } .u80cd417e0d52d681b5bf737911f1be3d { display: block; transition: background-color 250ms; webkit-transition: background-color 250ms; width: 100%; opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #95A5A6; } .u80cd417e0d52d681b5bf737911f1be3d:active , .u80cd417e0d52d681b5bf737911f1be3d:hover { opacity: 1; transition: opacity 250ms; webkit-transition: opacity 250ms; background-color: #2C3E50; } .u80cd417e0d52d681b5bf737911f1be3d .centered-text-area { width: 100%; position: relative ; } .u80cd417e0d52d681b5bf737911f1be3d .ctaText { border-bottom: 0 solid #fff; color: #2980B9; font-size: 16px; font-weight: bold; margin: 0; padding: 0; text-decoration: underline; } .u80cd417e0d52d681b5bf737911f1be3d .postTitle { color: #FFFFFF; font-size: 16px; font-weight: 600; margin: 0; padding: 0; width: 100%; } .u80cd417e0d52d681b5bf737911f1be3d .ctaButton { background-color: #7F8C8D!important; color: #2980B9; border: none; border-radius: 3px; box-shadow: none; font-size: 14px; font-weight: bold; line-height: 26px; moz-border-radius: 3px; text-align: center; text-decoration: none; text-shadow: none; width: 80px; min-height: 80px; background: url(https://artscolumbia.org/wp-content/plugins/intelly-related-posts/assets/images/simple-arrow.png)no-repeat; position: absolute; right: 0; top: 0; } .u80cd417e0d52d681b5bf737911f1be3d:hover .ctaButton { background-color: #34495E!important; } .u80cd417e0d52d681b5bf737911f1be3d .centered-text { display: table; height: 80px; padding-left : 18px; top: 0; } .u80cd417e0d52d681b5bf737911f1be3d .u80cd417e0d52d681b5bf737911f1be3d-content { display: table-cell; margin: 0; padding: 0; padding-right: 108px; position: relative; vertical-align: middle; width: 100%; } .u80cd417e0d52d681b5bf737911f1be3d:after { content: ""; display: block; clear: both; } READ: Critiqe On Kirstie Laird EssayFurther into the essay Lipset stated that America is the most legalistic, anti-statist, and rights oriented nation. In my words that is freedom, freedom, and freedom. I love freedom and the opportunity for more of it. Most people in the world want freedom and opportunity to gain more. That is why most of the worlds immigration is towards this great nation. Why is it that everybody knows about all these opportunities in America? It is because of the travelers, writers, and the list just goes on and on. With one good response to our country many people want to experience it themselves. Throughout Lipsetss essay he stated how America is different and how it has two sides of its own story. America started under rule and broke away from that for liberty and so on. It has been doing well but there is always a bad thing that comes from a good thing. Lipset calls this a double-edged sword. Some facts might state that things are great but other facts state that things are bad. Referring back to the first paragraph, America is great in many aspects but things do actually weigh is down. I am pleased to say that those great aspects is what keep us on top of the ?hill? that everybody is looking up to. History Essays

Should A Moment Of Silence Be Legal In Public Schools In 1962 The Sup

Should a "moment of silence" be legal in public schools? In 1962 the Supreme Court decided that public schools did not have the power to authorize school prayer. This decision made public school in the U.S. more atheistic than many European nations. For example, crosses still hang on the classroom walls in Poland, and the Ten Commandments are displayed in Hungary. There are prayers held at the beginning of legislative and judicial sessions and every President has mentioned a divine power in his inaugural speech. In keeping with a spirit of religious freedom as stated in the First Amendment, there is no reason why students should not be allowed to have a moment of silence during the school day when they can pray or do as they choose. The case Engel v. Vitale in 1962 decided that school prayer is unconstitutional. With this case, it was pointed out that the students were to "voluntarily" recite the following prayer: "Almighty God, we acknowledge our dependence upon Thee, and we beg Thy blessings upon us, our parents, our teachers, and our country." The court ruled that this rule was unconstitutional according to the First Amendment's "establishment clause," which states "Congress shall make no law respecting an establishment of religion." In response to the Engel v.Vitale case some schools adopted a "moment of silence." In 1963, another case was brought before the court dealing with school prayer, Abington School District v. Schempp. The Schempp family challenged a law in Pennsylvania requiring the students to say ten verses of the Bible before school. These readings from the Bible were declared unconstitutional. Members of the board felt reading the Bible would give the children more moral values. The Schempp family strongly disagreed. Members of Congress attempted to find a compromise. From this effort came the adoption of the moment of silence, which is guaranteed by the First Amendment's "Free Exercise" clause. Six states now permit silent moments -- Geo rgia, Virginia, Maryland, Mississippi, Tennessee, and Alabama. Silent prayer was ruled constitutional in 1985 as long as it had no religious intent or purpose. (Newsweek, October 3, 1994) Prayer has been banned in schools for thirty-three years. The moment of silence has been ruled constitutional, however. Every student fills a moment of silence in a different way: through song, a prayer, or a memory. Newsweek, October 3, 1994, vol. 124. U.S. News and World Report, December 5, 1995 Vol. 117, No. 22, pg. 8-9. The Case of Engel v. Vitale 370 U.S. 421 1962, p. 118-119. Abington School District v. Schempp 374 U.S. 203; 83 S. Ct. 1560; 10 L. Ed. 2d 844 1963, pg. 529-530. Should A Moment Of Silence Be Legal In Public Schools In 1962 The Sup Should a "moment of silence" be legal in public schools? In 1962 the Supreme Court decided that public schools did not have the power to authorize school prayer. This decision made public school in the U.S. more atheistic than many European nations. For example, crosses still hang on the classroom walls in Poland, and the Ten Commandments are displayed in Hungary. There are prayers held at the beginning of legislative and judicial sessions and every President has mentioned a divine power in his inaugural speech. In keeping with a spirit of religious freedom as stated in the First Amendment, there is no reason why students should not be allowed to have a moment of silence during the school day when they can pray or do as they choose. The case Engel v. Vitale in 1962 decided that school prayer is unconstitutional. With this case, it was pointed out that the students were to "voluntarily" recite the following prayer: "Almighty God, we acknowledge our dependence upon Thee, and we beg Thy blessings upon us, our parents, our teachers, and our country." The court ruled that this rule was unconstitutional according to the First Amendment's "establishment clause," which states "Congress shall make no law respecting an establishment of religion." In response to the Engel v.Vitale case some schools adopted a "moment of silence." In 1963, another case was brought before the court dealing with school prayer, Abington School District v. Schempp. The Schempp family challenged a law in Pennsylvania requiring the students to say ten verses of the Bible before school. These readings from the Bible were declared unconstitutional. Members of the board felt reading the Bible would give the children more moral values. The Schempp family strongly disagreed. Members of Congress attempted to find a compromise. From this effort came the adoption of the moment of silence, which is guaranteed by the First Amendment's "Free Exercise" clause. Six states now permit silent moments -- Geo rgia, Virginia, Maryland, Mississippi, Tennessee, and Alabama. Silent prayer was ruled constitutional in 1985 as long as it had no religious intent or purpose. (Newsweek, October 3, 1994) Prayer has been banned in schools for thirty-three years. The moment of silence has been ruled constitutional, however. Every student fills a moment of silence in a different way: through song, a prayer, or a memory. Newsweek, October 3, 1994, vol. 124. U.S. News and World Report, December 5, 1995 Vol. 117, No. 22, pg. 8-9. The Case of Engel v. Vitale 370 U.S. 421 1962, p. 118-119. Abington School District v. Schempp 374 U.S. 203; 83 S. Ct. 1560; 10 L. Ed. 2d 844 1963, pg. 529-530.

Succession Planning Essay Example

Succession Planning Essay Example Succession Planning Essay Succession Planning Essay The most significant organizational development issue for private and public sector organizations is how to identify, develop and retain talented leaders for the future. The key to any organizations success is the right people in place to lead tomorrow immersed in the organizations values so they can sustain the culture. Succession planning has also been identified as top factor for employee retention. The Succession Planning Process With KMx, you will be able to build the foundation for a customized succession planning process that will work specifically for the organization. KMx Performance Management enables you to put the groundwork into place today for developing the best talent at every level of the organization. By designing a performance management profile for every key Job in the organization you will be creating a succession planning roadmap for the future. Stage 1 Creation of Knowledge and Skill Profiles (KIS Tables) In KMx, KIS Tables are a listing of knowledge and skill behaviors associated with a particular subject area. KIS Tables are subdivided into types (normally knowledge and skill) and areas to further classify behaviors. KIS Table behaviors are sequenced in order of increasing complexity or logical progression. In addition to providing the primary content cataloging schema with KMx, KIS Table also provide the foundation for development of personnel labor classifications that are specific enough to support the succession planning process. Leveraging wizards provided by KMx, the organization will be able to quickly identify and document the key knowledge, skills and competencies to drive the performance management program and set the framework for a succession plan. Stage 2 Mapping organizational best practices and corporate values to create a succession planning program Mapping best practices to subject area behaviors (created during Stage 1) with organizational performance measures provides the measuring stick for performing an analysis of the gap between current personnel capabilities and the needs of the organization. In addition to this key element in the succession planning process, the indexes created during this phase are incredibly valuable for: Just-in- time performance support Curriculum maintenance Selection and certification of training materials The mapping process is central to the KMx architecture and is supported by expert system wizards to facilitate the effort. Stage 3 Create the plan and supporting documentation In KMx, personnel requirements are mapped to supporting content and to the behaviors, conditions and standards of the requirements. The indexes created by this mapping process provide the organization with the ability to perform continuous monitoring and development of the following key succession planning elements: Employee skills verification documentation Training continuum development and maintenance Individual career management and performance evaluations Organizational Leadership development and planning documentation Overall staff development and recruiting planning Stage 4 Execute the plan Succession planning requires executive sponsorship. KMx provides the technology, reports and structure to ensure a comprehensive plan. KMx will also provide the means to communicate, manage and deliver a meaningful performance management program that is coupled to the succession plan. What KMx can not provide is the leadership to implement the plan or the talent necessary to ensure the plans success. The executive sponsor of the organizations succession planning process must be prepared to accomplish the following tasks: Prioritize the key skill competencies that the organization requires for successful growth Link the corporate values and culture to the succession planning process Create an executive committee dedicated to driving the best talent forward Link performance management, training and recruiting processes to sharpen talent for he future Knowledge Management Solutions, Inc. rovides the technology and expertise to capture and index the knowledge and skills required for your organization to function at maximum efficiency and execute a successful succession plan. Our KMx technology platform organizes and delivers this information to the right people at the right time in context with the behaviors, conditions and standards of performance required to mee t the unique needs of the organization while providing executive management with the tools and reports necessary to plan for the future.

Rio Tinto Plc Essay Example | Topics and Well Written Essays - 1250 words

Rio Tinto Plc - Essay Example Japan will be importing huge amounts of aluminum, iron, and copper for its reconstruction projects. Three commodities which I liked from its product portfolio are gold, silver, and diamonds. The current price of gold in the international markets is $1452 per ounce (Goldprice, 2011). Diamonds have always been one of the most valuable stones in the world. Diamond jewelry can last a lifetime. There were other factors that attracted me towards selecting Rio Tinto as part of my portfolio. The firm had excellent revenues of $60,323 and net income of $14,324 in 2010. The net margin of the company is 23.74%. The company has a global workforce of 102,000 employees. The firm minimizes its risk by having a global operation located in Australia, North America, Asia, Europe and Southern Africa. The business risks of the company are also minimized by having a variety of products and working all sides of the mining industry supply chain. Two strengths of the company are its wide product range and strong market position. Two opportunities for the firm are the surging demand for gold and new investment and innovations. Throughout its history Rio Tinto has been known for its innovation in the mining industry. Rio Tinto is a solid investment that should pay off dividends both in t he short term and long term. HSBC Holdings Plc HSBC Holdings Plc is a banking and financial sector provider. The bank has an impressive customer portfolio of over 100 million customers worldwide. The company differentiates itself by providing a diverse range of banking and financial services. The firm has its corporate headquarters in London, United Kingdom. I liked the fact that the client base of the company included personal, commercial, corporate, and institutionalize investors. The firm has a network of 8000 offices across 88 countries. The banking industry has gone through a lot of changes since the global recession. The banks are now more risk averse which is a strategy that minimizes the risk of default on loans. Despite the losses that the industry incurred between 2007 and 2009 the banking industry had a solid recovery in 2010 (Plunkett Research, 2011). HSBC was one of the banks that were protected by the U.K. government during the recession. The fact that the government owns 41% of HSBC is an indicato r that the government will invest in HSBC to ensure its success. The global penetration of the company of having a physical presence in over 40% of the world’s countries is a good indicator of the success of the firm. Normally banks are more conservative in their selection of global expansion. The revenues of the company in 2010 were $62,096 million with net income of $5,834 million. The net margin off HSBC is 9.39%. The company has a global workforce of 289,435 employees. The market capitalization of the enterprise is $201,000 million. Two strengths of the bank are its strong capital base and brand perception. The company could take advantage of strategic acquisitions and growth by expansion in emerging markets. The firm could achieve significant growth by penetrating new locations. The favorable forecast for the industry was a factor that made me invest in HSBC. BT Group Plc BT Group Plc is a UK based communication company. The firm is considered one of the world’s l eading communication companies. BT has been able to penetrate the communications marketplace at over 170 countries around the world. The services offered by the company includ

Should Everyone be Equal in the Society Essay Example | Topics and Well Written Essays - 250 words

Should Everyone be Equal in the Society - Essay Example At only 14 years old, Harrison Bergeron tries to break down the equality that has engulfed the entire country including his father. Handicapper general ensures that she monitors any bright person who tries to think beyond the normal reasoning capacity. Individuality in this society is no more. This is evident when the handicapper general guns down Harrison Bergeron and her empress. Hidden individuality is also evident when the presenter who reads the press conference does the reading while wearing a mask since she is pretty. Because Harrison is more handsome and stronger, he gets to carry the heaviest load of handicaps to weaken him. The tone of the story varies from fearful to happiness but ends up in a somber mood when main characters end up dead. Happy mood is evident when Harrison frees everyone in the studio from the slavery of wearing handicaps and dancing sets in.

Protestantism Essay Example | Topics and Well Written Essays - 1250 words

Protestantism - Essay Example And also their belief system compels them to save more in order to defer gratification, which transforms into investments and thus higher productivity in the longer run. This was suggested in Max Weber's The Protestant Ethic and the Spirit of Capitalism that a "Protestant ethic" was instrumental for economic progress, several interpretations have emerged how the greater economic affluence of Protestants relative to Catholics might have come about. The idea of Weber that Protestantism has a great impact on the economic progress of a country was depicted in Figure 2,3a and 3b. But not all areas in Prussia have exhibited the jolt of Protestantism to their economic status. Figure 2 has revealed a concentric pattern of the diffusion of Protestantism with Wittenberg at the centre. There was a marked x in Wittenberg, to emphasize the distance from the areas with dominant protestant population. The central, north and the north-eastern part of Prussia is predominantly Protestant, which accounts more than 75 % of their population. Protestant diffusion came to a halt in the western provinces (Rhineland and Westphalia) and in the eastern parts which were predominantly Polish speaking. As a general tendency, the predominantly Protestant regions in the centre of Prussia are also economically more successful (Figures 3a and 3b). Another centre of economic progressiveness is the western rural area with its mineral resources, in which not all residents were Protestants. The idea of having a positive correlation between Protestantism and the growth of per capita income in Prussia does not hold in the North-eastern and the Western Part of the region. The north-eastern part has a predominantly protestant population but it was not reflective to the percentage share of employment in manufacturing and services, they only have less than 22% share. In the western part, in which less than 22% of the population were Protestants, revealed a larger share of employment in manufacturing and services with more than 30% Becker and Woessmann have disputed Weber's idea that Protestantism itself generates greater growth. They have suggested that higher literacy among Protestants was responsible for greater growth of per capita income; it's not because of religion alone. The idea of Becker and Woessmann of literacy being the key factor to economic progress was base on Luther's Educational Postulations. Luther was the first one to translate the Latin Bible into German. His idea of convincing people to read the gospel, instead of a priest reading it to them, has lead to his advocacy of teaching them to read (in order for them to understand the bible). Luther has explicitly urged for the expansion of education (cf. Rupp 1996a, 1996b, 1998). Quite obviously, if one wants to read the Bible, one must be able to read. Very early on, in what is generally viewed his first major pamphlet that signified the breakthrough of the Reformation among the general public, To the Christian Nobility of the German Nation Concerning the Reform of the Christian Estate, Luther (1520, pp. 461-462) explicitly demanded that every town should have both a boys' and a girls' school where every child should learn to read the Holy Scriptures, in particular the Gospel. Luther's call to teach everyone in order for them to be able to read God's Word by themselves is the key feature for our alternative theory of the relative

Impact of Organised Retail On Unorganised Retail

Impact of Organised Retail On Unorganised Retail Abstract The revolution in Indian retail industry has brought many sweeping changes and also opened door for many Indian as well as foreign players. In Indian scenario there is always a constant clash between challenges and opportunities but chances favors those companies that are trying to establish themselves. As every coin has two faces similarly it also has some pros and cons. In India about 96% of retail markets consist of unorganized retail players such as kirana stores. As a result of favorable demographic conditions such as changing life style of Indian consumers and government policies provide huge opportunities for Indian corporate houses as well as foreign players. If we compare today’s scenario with earlier we found that at that time the price and the delivery mode is totally different .at present the markets and their processes are more flexible in all aspects. The new Snow-white market places have started to replace the traditional bazaar – kind of dwarfed tiny corner kirana shop. India has highest shop density in the world. It has more than 1.5crores retail shop thus providing 2nd highest employment after agriculture. It employs 7% of total workforce and contributing more than 10% of India’s GDP.But have we ever thought that what by the entry of big retailers what will be happened to those unorganized retail kirana stores which constitute 96% of it? It may not have an immediate effect but in long run it might affect the small kirana stores and thus many people would loose there job , many families could get affected thus in long run we should not ignore this issue . The main purpose of this report to study the impact of organized retail on the small kirana stores and to find: How kirana stores can sustain themselves in long run? How they will cope in the competition from organized retail players? Are the steps taken by government enough for their safeguards? This paper discusses the various challenges faced by both organized as well as kirana stores in Delhi NCR and how both can sustain in equilibrium without much affecting each others. Introduction Retailing can be defined as the sale of goods or merchandise, from a fixed location such as a department store or kiosk, in small or individual lots for direct consumption by the consumer. Retailing is a well recognized business function which compromises making available desired product in the desired quantity at the desired time. This creates a time, place and form utility for the consumer. The success of retailing is depend up on the efficient supply chain and assortment of merchandise mix. A well-developed supply chain reduces wastages and transaction cost thereby reducing the cost of inventories to be maintained by the producers and the traders. A reduction in the cost of inventory management leads to a reduction in the final price to the consumer. Retailing has been identified as a key source for promotion of textiles, processed foods, agricultural and horticultural products. Recently due to certain demographic and economic changes India retail sector has taken a new breathe. It has created a lot of opportunities for big corporate houses like Tatas , Reliance and Bharti etc as well as for many foreign players. As in present scenario Indian retail is in nascent stage therefore it is not much affecting the small kirana stores but in long run its affect can be ignore. Undoubtedly, revolution in retail is good for Indian consumers as well as government as it will increase the taxes i.e. income for government and consumer will have more choice. Broadly Indian retail sector can be classified into two segments: Unorganized retailing Unorganized retailing is characterized by a distorted real-estate market, poor infrastructure and inefficient upstream processes, lack of modern technology, inadequate funding and absence of skilled manpower. Therefore, there is a need to promote organized retailing. Organized Retailing Organized Retailing can be defined as a form of retailing whereby customers can buy goods in a similar purchase environment across more than one physical location for verticals from food, grocery, apparel, consumer durables, jewellery, footwear, beauty care, home dà ©cor, and books to music. In organized retailing a proper record is maintain by the government and retailers need to pay the tax to the government. What is the threat for local organized stores? India has highly fragmented retail industry. Today’s scenario India, still have of the traditional formats retailing .Today still local kirana shop, pan, bidi shop, hardware Store, weekly hatts,convenience stores bazaars etc.It constitute about 96% of retail market .About 12 million outlets operating in country and only 5% of them being larger than 500 square feet in size. In India it is very important to understand what role it pays in lives of Indian citizens from social as well as economic prospective. Retailing is probably the primary form of Disguised Unemployment In Our Country As we have over crowded agriculture sector and stagnating manufacturing sector and the low wages and hard work in both sectors forced many Indians to jump in service sector. Here due to lack of opportunities it is almost become a natural decision for an individual to set up a small shop or store depending upon his financial condition .Thus retailer is born by circumstance not by choice. Ultimately it provides job of more than 6 crores people where as organized retail provides employment to roughly 7 lakhs peoples. So the policy makes should be careful about these 6 crores peoples, whose livelihood may get in danger in future. Retail Industry Structure Global Scenario Worldwide retail industry is one of the most attracting industry being controlled by a handful of powerful corporations based mainly in the U.S and Europe, namely, Wal-Mart, Tesco, Carrefour and Metro. Beside these their are many others big MNC retailers but they have saturated in their home countries only and are looking for penetrating emerging markets like India, China and Russia. As these players are penetrating in these countries thus providing a world class shopping experience to the consumers. Today consumers become more demanding want world class products as well as not only buying but an experiential shopping. Thus shift in consumer behavior in these emerging markets attracting world biggest players. Also the saturation in US retail market and other existing markets in developed countries forcing them to move in new market like India and china. Retailing in United States Retail Sector is the second largest industry in U.S. both in number of establishments and number of employees. The U. S. retail industry generates $3.8 trillion in retail sales annually ($4.2 trillion if food service sales are included), that is approximately $11,993 per capita. Wal-Mart is the worlds largest retailer and the worlds largest company with more than $312 billion (USD) in sales annually. Wal-Mart employs 1.3 million associates in the United States and more than 400,000 internationally. The second largest retailer in the world is Frances Carrefour. Retail Trends in other Countries China had initially restricted FDI in retailing to only joint ventures at 49 percent foreign holding and only at specified locations subject to a ceiling on the number of stores. Malaysia, Indonesia, Thailand and Japan have enforced zoning restrictions for mega-retailers. There are minimal capital requirements for foreign retailers in Sri Lanka. The Philippines has imposed â€Å"sourcing† and reciprocity requirements on foreign retailers. In Japan, mega-retailers must seek the views and permission of small local stores before opening a new store. In the US, major cities such as Los Angeles, California, Chicago and New York City have restricted the opening of Wal-Mart stores within city limits. France enacted the Raffairin Act that regulates the growth of hypermarkets larger than 300 square feet. In Thailand, the government has set up an assistance fund for local retailers due to the impact of mega retailers. Share of Retail Market in world economy: Country Total Market ( bn US $) U.S 4030 Taiwan 40 Malaysia 20 Thailand 32 Indonesia 75 China 325 India 360 Indian Retail Scenario History Traditionally Indian Retail can be traced back from Weekly Markets, Melas, Village Fairs in Small towns and villages to Kirana stores, PDS outlets, Khadi Bhandaar, co-operative stores in Urban cities. The wave of retail began with various textile manufactures like Bombay Dyeing, Raymonds, S Kumar’s, and Grasim foraying into selling the product through their outlets and competition among FMCG players driving the forces towards retailing. The evolution of retailing lead to an emergence of various modern formats like Shopping malls, Super-marts, Hyper-marts,Departmental Stores, Apparel Stores, etc. catering to majorly all sectors of society providing the all-important 3Vs – Value, Variety and Volume. Retail Boom In India Indian Retail Sector is at its inflexion point awaiting multifold growth. The Retail Industry’s Size is presently Rs 1, 44,253 crores out of which the organized sector contributes to a mere 4 percent Of the market size, fairly dominated by scattered, unregulated, unorganized players. Retail sector is expected to grow in tandem to the GDP growth-rate. This sector is slated to be the biggest contributor to GDP of around 10 percent and has promisingly generated ~8 percent employment in India, which is moving towards a larger generation of employment opportunities in the times ahead. Future Of Organised Retailing In India Due to the urban-rural divide, organised retail will grow in the metros and large cities, followed by semi-urban and rural areas. Thus India is on the verge of an enormous multi-fold growth of organised retail. In a span of just 5 years, organised retail is expected to expand in urban cities besides making an entry in semi-urban and rural areas. Presently, the organised retail market is 4 percent of the total retail, that is around Rs 67,310 crore and is expected to compound at 27 percent per annum, aggregating to Rs 1,75,103 crore (7.44 percent of the total retail) in 2010-11. The retail industry is assumed to grow at GDP growth rate. The retail revolution signals softening of inflation rate on an yearly basis, due to elimination of intermediaries in retailing and passing on of all the benefits to the consumer. The mantra expediting the retail growth is ‘Consumer is the King’. Penetration of Organized Sector Organized Share of retail sector is expected to increase to 8-9 percent in 2010-11 from 4 percent in 2007. Segmental Growth of Retailing Food and Grocery This is the largest vertical of 74.4 percent of retail size compromising fruits and vegetables, milk and milk products, staples, cereals, grains, pulses, processed food, ready to cook and ready to eat meals, spices and other eatables. This is least penetrated segment across all verticals of around 1.5 percent, being the most untapped pie. According to NSSO 60th round, 54 percent of the rural and 42 percent of urban expenditure was on food. Apparels Clothing and textile is a large organized vertical dominated by textile manufacturers Raymond, Bombay Dyeing, Vimal, and by big retailers like Pantaloon, Pyramyd, Koutons having ~16.4 penetration level. Increasing disposable incomes and change in the lifestyle needs has pushed the segment. Consumer Durables The electronics and consumer durable is the biggest organized segment penetrated to ~20 percent. There lies more unearthed growth in the verticals as the craze for electronic gadgets have been picking up with the advent of nuclear families. Home Dà ©cor and furnishing The demand for furnishing is going to be spearheaded by a huge demand for the real-estate, paving way to tap the unorganized segment. Presently only a few players like Gautier, Godrej, Durian function as organized entities. Jewellery and Watches Titan is the early entrant in the segment followed by MNCs Oyzterbay, Tanishq, Swaroski, Orra, Gitanjali, D’damas driven by demand for fashion accessories, and huge advertising and promotion campaigns. Beauty Care The organised players in Beauty Care are HLL (Lakme Salons), Marico (Kaya), Health and Glow are having a huge growth impetus. Footwear Leaving aside the Apparel, Footwear segment is forming a big pie in the organised retail sector, expected to grow to greater heights with foreign payers like Crocs Inc. Books, Music and gifts In addition to Tier-II and Tier-III cities, the habit of reading books and listening to music is picking up among the Tier-I cities. The stores like Oxford Bookstore etc are experiencing this upswing. Organized Retail Growth in Indian Cities The Retail sector contributes to around 36 percent of GDP in India and is largest employment generator. The sector is dominated by small-scattered unorganised regional players, large players contributing to meager 10 percent of the total pie. Organised retail is at its nascent phase wherein the large organised retail groups are having aggressive expansion plans to penetrate the Metros and Tier I cities and establish themselves amongst rural masses of Tier I and Tier II cities. There lies a challenge for retailers to experiment with new value formats along with developing customer loyalties. Since there will be demographic shift in population growth, urbanization and migration due to transition in urban household growth and income distribution. The total retail market in the top 67 cities in India in 2006 was Rs. 2.55 trillion, which is expected to increase to Rs. 3.91 trillion in 2011. According to CRISIL, around 87 percent of the retail opportunity comes from top 25 cities compromising Metro Delhi, Mumbai, Calcutta, Mini Metros Hyderabad, Chennai, Bangalore, Mini Metros Ahmedabad and Pune, Tier I cities of Kanpur , Nagpur, Surat and Ludhiana, Tier II cities Coimbatore, Chandigarh, Lucknow, Kochi, Jaipur and Tier III cities Vadodara, Vizag, Indore, Vijaywada, Thiruvananthpuram, Bhopal, Nashik and Madurai. The levels of penetration in the top 67 cities are expected to leap. Organized retail has been established in Metros and Tier 1 cities, other cities having negligible level of penetration Retail Formats in India: Conventional Formats Kirana These are food and non-food neighborhood counter stores, also called ‘mom and pop stores’ in western countries. These are big chunks forming the segregated and unorganised retail segment. These are family-ownedand- run retail-outlets picking the goods from wholesalers totaling to around 12 million stores across India. Mandis These are the largest chunk of unorganised retail catering to urban and rural masses. Mandis are physically located at different regions to enhance convenient shopping. The sellers bring across various products like eatables,vegetables and fruits, pulses, cereals, spices etc. The most prominent of them are sabzi mandis found in most of the localities across India. Village Haats This form is operating in rural areas where buyers and sellers gather once in a week or month from nearby villages and small towns to cater their livelihood and leisure needs. These haats are a source of entertainment and socialization among rural masses. Push Cart Vendors The are categories of vendors roaming from door to door in various localities selling fruits, vegetables, and other eatables, from which mostly housewives makes purchases that too on credit. Modern organized retail formats: Shopping malls Area -60000-700000 square feet Point of differentiation: Multi format, Multi products, Multi brand caterings, Lifestyle needs. Hyper market Area: 50000 – 100000 square feet Point of differentiation: Multi vertical Super markets Area: 5000-10000 square feet. Point of differentiation: low cost, low margin high volume, self service operations design to serve total need for food, laundry household maintenance products. Departmental stores Area: 20000-30000 square feet. Point of differentiation: single vertical , several product lines Apparels store Area: 20000-25000 square feet Point of differentiation: Multi branded, Single vertical, focusing on high consumers Specialty stores Area:-2000-5000 square feet Point of differentiation: Narrow product line with deep assortment ,multi branded, Single vertical on specific needs of the customers. Exclusive formats Area: 500-5000 square feet Point of differentiation: Owned/Franchised, Single products 8. Convenience stores Area: 200-500 square feet Point of differentiation: Located near residential area, open long hours, seven days in a week, limited product line, high turnover Advantages of conventional Modern Organized retail formats Conventional formats: Low operating cost Overheads. Proximity to consumers. Low operating hours. Strong relations with customers. Modern organized retail formats: Large bargaining power with suppliers. Range variety of goods. Quality assurance( Brand related, durability) Convenience Hygiene Business Models suiting Indian Scenario Cash--carry Wholesale Model Cash--carry is a form of retail trade in which goods are sold from a wholesale warehouse operated either on a self-service basis where customers settle the invoice on-the-spot or pay cash and carry the goods away themselves. The cash--carry player also performs many value-added functions, including selling and promoting, buying and assortment building, bulk-breaking, warehousing, transporting, financing, risk-bearing, supplying market information, and providing management services. Hub-and-spoke Model Retail Chains are entering residential areas with the hub-andspoke model, whereby one large store supports various smaller stores in the nearby residential areas. This is win-win model is well-suited to the Indian business scene where large stores obtain supplies from the warehouse and supplies to the consumers, involving both large payers acting as wholesalers and local kiranas as retail outlets. With efficient supply chain management, availability of space and proper technology in place, this will not take much time. The Piramyd Retail’s Trumart Stores (food and grocery) in Mumbai and Pune are based on a similar model. Growth Enabling Factors Higher Disposable Income The disposable income has been showing a rapid increase from the last few years and is expected to grow steadily because the proportion of the major consuming class (population having incomes higher than Rs 90,000) is expected to reach 48 percent by 2009-10 from 20 percent in 1995-95, at the 2001-02 prices, at a CAGR of 9.3 percent over the next 8 years leading to new consumption patterns due to increasing depth in the consumers’ pocket. Growing Working women population The propensity to spend in the case of working women is higher by 1.3 times as compared by housewives. According to the census report, the population of working women increased to 26 percent in 2001 as compared to 22 percent in 1991. Adoption of Nuclear Family culture The increase in per capita income paved way to increase the nuclear-family culture. The proportion of nuclear families as a percentage of total household population has increased as shown by fall in average household size from 5.57 in 1991to 5.36 in 2007, expected to fall further to 5.02 by 2011. This will fuel the growth of organised retail. Baby Boomer Effect The demographics of Indian population has a steep growth in earning population (15-60 yrs). In 2000, 593 million people (58.3 percent of total population) constituted the age bracket of 15-60 yrs – growing from an unprecedented level of 335 million people (54 percent of total population) in 1975 at a rate of 77 percent (CAGR of 2.3 percent) in contrast to a population growth of 64 percent (CAGR of 2 percent) over the same period of 25 years. Over the next 15 years, the earning population is expected to increase to 62.8 percent in 2015, translating into a population of 782 million. Growth in Urban Population Urbanization has increased at a rate of 2.7 percent over the last 10 years (1990-2000). In 2000, the urban population was estimated to be 281 million (27.7 percent of the total population). This trend is likely to continue and urbanization is expected to grow at 2.4 percent between 2000 and 2015. In 2015 the urban population is expected to be 401 million, constituting 32.2 percent of the total population. Robust Outlook towards Branded products Due to liberalization of manufacturing sector, various organized branded products have entered into Indian markets, thereby developing and widening the basket for branded finished goods. With the advent of International competition, new trends and lifestyles are evolving among India masses resulting into 10-15 percent growth in branded products. This has established the base for organized retail market in India. Growth in Retail Malls and various other new Formats Real Estate players like Raheja’s, Future Group, DLF, Omaxe, Piramal Group, Parsvnath, Unitech are developing retail malls and leasing out the retail spaces to various retailers of varied products making it a one-stop shopping destinations in urban and semi-urban cities. These shopping-cum-entertainment malls are wooing young buyers to increase their conversion rate backed by increasing foot-falls. Around 358 malls have come up by 2007, covering a total space of 87 million square feet, thereby pushing organised retail to new heights. Plastic Money becoming a greater Pie of credit The use of plastic money in the form of debit and credit cards has expanded multifold in last 5 years. The number of credit cards has grown at a CAGR of 28 percent and debit cards galloped by 140 percent. The customers have adopted the habit of electronic payments and leveraging their pockets shifting from basic needs to lifestyle products. Swot Analysis of Organized Stores Strength: As being technology intensive .these stores are able to forecast customer demand, shorten lead time reduce inventory holding ultimately save cost. Wide assortment show customer has variety of choice Weakness: Despite of high footfall the conversion rate is very low. As a result retail measure experiencing an ROI of only 8% to 10% Organized stores have less customer loyalty as compare to unorganized stores. Low customer knowledge Lack of personal touch Opportunities: Indian middle class is already 30 crores projected to grow to over 60 crores by 2010 making India one of the largest consumer markets in the world. According to KSA projections by 2015 India will have 55 crores people under the age of 20 reflecting the enormous opportunities possible in the kids teens retailing segments. Threats: High real estate rent. Poor Infrastructure Less develop shopping culture. Due to fragmented market high distribution cost. Swot Analysis of Unorganized Stores Strength: Located in prime residential area. Rental for large stores in these area are generally not available. They enjoy a near monopoly in area that is backward or do not have a population with sustainable purchasing power like rural areas. since organized retailer are unlikely to enter such reasons Weakness: Do not provide quality assurance. Less concern about ambience hygiene issue. Opportunities: Low capital requirements Proximity to consumers and strong relationship help them to gauge .Customer needs stock accordingly thus gaining more business. Threats: Increase in use of credit cards With huge stores coming up in catchments areas of 5-7 km of approachable distance larges chains planning to set up hub spoke, smaller stores. So the very existence of traditional store is in danger. Low or no bargaining power due to small scale of operations Due to smaller in size unable to stock a variety of goods. Provide not many options to the customers. Why Indian consumers want more experiential shopping today? The Indian consumer is changing rapidly. The average consumer today is richer, younger and more aspirational in his or her needs than ever before. Consumers now value convenience and choice on a par with getting value for their hard-earned money. A range of modern retailers is attempting to serve the needs of the ‘new’ Indian consumer. Today Indian consumers want not only buying but a full shopping experience. For this one of the important factors responsible is change in life style as well as disposable income. As per Indian consumer’s map , approximately 209 million of total household in India 6 millions are rich having annual income of more than US$ 4700 .this number were 1 million household in 1994 and 3 million households in 1999-00 thus this class is growing very rapidly. About 50% of these families are living in metros and spending more than eighteen billion annually. As per the need of these families around 62% market for premium products is concentrated in Mumbai, Bangalore, Chennai and Kolkata. But now retail market is moving toward big and also small cities . India’s 8.5% of the retail market concentrated in 8 big cities .As per an estimate among rich class top most 1 million customers comes under superrich category growing by 20% per annum and shows behavior similar to international consumers . While this segment is worth targeting for high-end premium products, it is not the key driver of the organized retail sector. The real driver of the Indian retail sector is the bottom 80% of the first layer and the upper half of the second layer of the income map (see ‘Map of India’s income classes’ below). This segment of about 40 million households earns USD 4,000-10,000 per household and comprises salaried employees and self-employed professionals. This segment is expected to grow to 65 million households by 2010 and is currently the key driver behind explosive growth in passenger car sales (USD 5 billion in 2004) and mobile phone penetration (over 70 million). The top 6 Indian cities -Mumbai, Delhi, Chennai, Kolkata, Bangalore and Hyderabad -are the darlings of India’s exploding economy. They represent 6% of the population, but contribute 14% of India’s GDP. They are the centers of business, finance, politics and the emerging sunrise industries such as IT, pharma and ITeS, which have put India on the global map. These cities are also the barometer of India’s economic development and most foreign investors have flocked here. Are Indian consumers are ready for organize retail? By the end of 20th century in Indian retail sector too many significant changes has taken place. The retailing industry, which in early1990s was dominated by the unorganized sector, is now going a drastic change with a rapid growth in the organized sector with the entry of many corporate groups such as Tata, RPG, ITC and Bennett Coleman Company. Now Indian consumers are much aware about domestic and foreign products by the different source of media, such as newspaper ,television and the internet Apart from this there are too many social changes like increase in working couples , increase in number of nuclear families , rapid Urbanization.goverment policies ,increase in availability of retail space , increase in disposable income , availability of educated manpower also catalyzed the growth of organize retail . Food retailing was the most important area where players like food worlds establishing their outlets all over the India. Beside it supermarket and departmental stores now replacing traditional grocery stores all over the India , by the entry of fast foods (McDonalds), packaged foods (MTR), vending machines and specialty beverage parlors (Nescafe, Tata Tea, Cafe Coffee and Barista) brought about significant changes in the eating habits of Indian consumers. Literature Review Indian retail sector still has long way to go till now many research work and articles have been return over Indian retail. These articles and research work mainly focus upon huge untapped markets in Indian retail. They mainly talk about the opportunities available in the Indian market for the growth of organized retail. Some of the important research paper and articles which inspired me and catalyzed my thinking process over this topic are: â€Å"The evolving retail market in India† was written by Dale Anne Raiss and Ranjan biswas working as partner and head of market at Ernst Young .In this report they talk about largely untapped potential in retailing in India. They also tal Impact of Organised Retail On Unorganised Retail Impact of Organised Retail On Unorganised Retail Abstract The revolution in Indian retail industry has brought many sweeping changes and also opened door for many Indian as well as foreign players. In Indian scenario there is always a constant clash between challenges and opportunities but chances favors those companies that are trying to establish themselves. As every coin has two faces similarly it also has some pros and cons. In India about 96% of retail markets consist of unorganized retail players such as kirana stores. As a result of favorable demographic conditions such as changing life style of Indian consumers and government policies provide huge opportunities for Indian corporate houses as well as foreign players. If we compare today’s scenario with earlier we found that at that time the price and the delivery mode is totally different .at present the markets and their processes are more flexible in all aspects. The new Snow-white market places have started to replace the traditional bazaar – kind of dwarfed tiny corner kirana shop. India has highest shop density in the world. It has more than 1.5crores retail shop thus providing 2nd highest employment after agriculture. It employs 7% of total workforce and contributing more than 10% of India’s GDP.But have we ever thought that what by the entry of big retailers what will be happened to those unorganized retail kirana stores which constitute 96% of it? It may not have an immediate effect but in long run it might affect the small kirana stores and thus many people would loose there job , many families could get affected thus in long run we should not ignore this issue . The main purpose of this report to study the impact of organized retail on the small kirana stores and to find: How kirana stores can sustain themselves in long run? How they will cope in the competition from organized retail players? Are the steps taken by government enough for their safeguards? This paper discusses the various challenges faced by both organized as well as kirana stores in Delhi NCR and how both can sustain in equilibrium without much affecting each others. Introduction Retailing can be defined as the sale of goods or merchandise, from a fixed location such as a department store or kiosk, in small or individual lots for direct consumption by the consumer. Retailing is a well recognized business function which compromises making available desired product in the desired quantity at the desired time. This creates a time, place and form utility for the consumer. The success of retailing is depend up on the efficient supply chain and assortment of merchandise mix. A well-developed supply chain reduces wastages and transaction cost thereby reducing the cost of inventories to be maintained by the producers and the traders. A reduction in the cost of inventory management leads to a reduction in the final price to the consumer. Retailing has been identified as a key source for promotion of textiles, processed foods, agricultural and horticultural products. Recently due to certain demographic and economic changes India retail sector has taken a new breathe. It has created a lot of opportunities for big corporate houses like Tatas , Reliance and Bharti etc as well as for many foreign players. As in present scenario Indian retail is in nascent stage therefore it is not much affecting the small kirana stores but in long run its affect can be ignore. Undoubtedly, revolution in retail is good for Indian consumers as well as government as it will increase the taxes i.e. income for government and consumer will have more choice. Broadly Indian retail sector can be classified into two segments: Unorganized retailing Unorganized retailing is characterized by a distorted real-estate market, poor infrastructure and inefficient upstream processes, lack of modern technology, inadequate funding and absence of skilled manpower. Therefore, there is a need to promote organized retailing. Organized Retailing Organized Retailing can be defined as a form of retailing whereby customers can buy goods in a similar purchase environment across more than one physical location for verticals from food, grocery, apparel, consumer durables, jewellery, footwear, beauty care, home dà ©cor, and books to music. In organized retailing a proper record is maintain by the government and retailers need to pay the tax to the government. What is the threat for local organized stores? India has highly fragmented retail industry. Today’s scenario India, still have of the traditional formats retailing .Today still local kirana shop, pan, bidi shop, hardware Store, weekly hatts,convenience stores bazaars etc.It constitute about 96% of retail market .About 12 million outlets operating in country and only 5% of them being larger than 500 square feet in size. In India it is very important to understand what role it pays in lives of Indian citizens from social as well as economic prospective. Retailing is probably the primary form of Disguised Unemployment In Our Country As we have over crowded agriculture sector and stagnating manufacturing sector and the low wages and hard work in both sectors forced many Indians to jump in service sector. Here due to lack of opportunities it is almost become a natural decision for an individual to set up a small shop or store depending upon his financial condition .Thus retailer is born by circumstance not by choice. Ultimately it provides job of more than 6 crores people where as organized retail provides employment to roughly 7 lakhs peoples. So the policy makes should be careful about these 6 crores peoples, whose livelihood may get in danger in future. Retail Industry Structure Global Scenario Worldwide retail industry is one of the most attracting industry being controlled by a handful of powerful corporations based mainly in the U.S and Europe, namely, Wal-Mart, Tesco, Carrefour and Metro. Beside these their are many others big MNC retailers but they have saturated in their home countries only and are looking for penetrating emerging markets like India, China and Russia. As these players are penetrating in these countries thus providing a world class shopping experience to the consumers. Today consumers become more demanding want world class products as well as not only buying but an experiential shopping. Thus shift in consumer behavior in these emerging markets attracting world biggest players. Also the saturation in US retail market and other existing markets in developed countries forcing them to move in new market like India and china. Retailing in United States Retail Sector is the second largest industry in U.S. both in number of establishments and number of employees. The U. S. retail industry generates $3.8 trillion in retail sales annually ($4.2 trillion if food service sales are included), that is approximately $11,993 per capita. Wal-Mart is the worlds largest retailer and the worlds largest company with more than $312 billion (USD) in sales annually. Wal-Mart employs 1.3 million associates in the United States and more than 400,000 internationally. The second largest retailer in the world is Frances Carrefour. Retail Trends in other Countries China had initially restricted FDI in retailing to only joint ventures at 49 percent foreign holding and only at specified locations subject to a ceiling on the number of stores. Malaysia, Indonesia, Thailand and Japan have enforced zoning restrictions for mega-retailers. There are minimal capital requirements for foreign retailers in Sri Lanka. The Philippines has imposed â€Å"sourcing† and reciprocity requirements on foreign retailers. In Japan, mega-retailers must seek the views and permission of small local stores before opening a new store. In the US, major cities such as Los Angeles, California, Chicago and New York City have restricted the opening of Wal-Mart stores within city limits. France enacted the Raffairin Act that regulates the growth of hypermarkets larger than 300 square feet. In Thailand, the government has set up an assistance fund for local retailers due to the impact of mega retailers. Share of Retail Market in world economy: Country Total Market ( bn US $) U.S 4030 Taiwan 40 Malaysia 20 Thailand 32 Indonesia 75 China 325 India 360 Indian Retail Scenario History Traditionally Indian Retail can be traced back from Weekly Markets, Melas, Village Fairs in Small towns and villages to Kirana stores, PDS outlets, Khadi Bhandaar, co-operative stores in Urban cities. The wave of retail began with various textile manufactures like Bombay Dyeing, Raymonds, S Kumar’s, and Grasim foraying into selling the product through their outlets and competition among FMCG players driving the forces towards retailing. The evolution of retailing lead to an emergence of various modern formats like Shopping malls, Super-marts, Hyper-marts,Departmental Stores, Apparel Stores, etc. catering to majorly all sectors of society providing the all-important 3Vs – Value, Variety and Volume. Retail Boom In India Indian Retail Sector is at its inflexion point awaiting multifold growth. The Retail Industry’s Size is presently Rs 1, 44,253 crores out of which the organized sector contributes to a mere 4 percent Of the market size, fairly dominated by scattered, unregulated, unorganized players. Retail sector is expected to grow in tandem to the GDP growth-rate. This sector is slated to be the biggest contributor to GDP of around 10 percent and has promisingly generated ~8 percent employment in India, which is moving towards a larger generation of employment opportunities in the times ahead. Future Of Organised Retailing In India Due to the urban-rural divide, organised retail will grow in the metros and large cities, followed by semi-urban and rural areas. Thus India is on the verge of an enormous multi-fold growth of organised retail. In a span of just 5 years, organised retail is expected to expand in urban cities besides making an entry in semi-urban and rural areas. Presently, the organised retail market is 4 percent of the total retail, that is around Rs 67,310 crore and is expected to compound at 27 percent per annum, aggregating to Rs 1,75,103 crore (7.44 percent of the total retail) in 2010-11. The retail industry is assumed to grow at GDP growth rate. The retail revolution signals softening of inflation rate on an yearly basis, due to elimination of intermediaries in retailing and passing on of all the benefits to the consumer. The mantra expediting the retail growth is ‘Consumer is the King’. Penetration of Organized Sector Organized Share of retail sector is expected to increase to 8-9 percent in 2010-11 from 4 percent in 2007. Segmental Growth of Retailing Food and Grocery This is the largest vertical of 74.4 percent of retail size compromising fruits and vegetables, milk and milk products, staples, cereals, grains, pulses, processed food, ready to cook and ready to eat meals, spices and other eatables. This is least penetrated segment across all verticals of around 1.5 percent, being the most untapped pie. According to NSSO 60th round, 54 percent of the rural and 42 percent of urban expenditure was on food. Apparels Clothing and textile is a large organized vertical dominated by textile manufacturers Raymond, Bombay Dyeing, Vimal, and by big retailers like Pantaloon, Pyramyd, Koutons having ~16.4 penetration level. Increasing disposable incomes and change in the lifestyle needs has pushed the segment. Consumer Durables The electronics and consumer durable is the biggest organized segment penetrated to ~20 percent. There lies more unearthed growth in the verticals as the craze for electronic gadgets have been picking up with the advent of nuclear families. Home Dà ©cor and furnishing The demand for furnishing is going to be spearheaded by a huge demand for the real-estate, paving way to tap the unorganized segment. Presently only a few players like Gautier, Godrej, Durian function as organized entities. Jewellery and Watches Titan is the early entrant in the segment followed by MNCs Oyzterbay, Tanishq, Swaroski, Orra, Gitanjali, D’damas driven by demand for fashion accessories, and huge advertising and promotion campaigns. Beauty Care The organised players in Beauty Care are HLL (Lakme Salons), Marico (Kaya), Health and Glow are having a huge growth impetus. Footwear Leaving aside the Apparel, Footwear segment is forming a big pie in the organised retail sector, expected to grow to greater heights with foreign payers like Crocs Inc. Books, Music and gifts In addition to Tier-II and Tier-III cities, the habit of reading books and listening to music is picking up among the Tier-I cities. The stores like Oxford Bookstore etc are experiencing this upswing. Organized Retail Growth in Indian Cities The Retail sector contributes to around 36 percent of GDP in India and is largest employment generator. The sector is dominated by small-scattered unorganised regional players, large players contributing to meager 10 percent of the total pie. Organised retail is at its nascent phase wherein the large organised retail groups are having aggressive expansion plans to penetrate the Metros and Tier I cities and establish themselves amongst rural masses of Tier I and Tier II cities. There lies a challenge for retailers to experiment with new value formats along with developing customer loyalties. Since there will be demographic shift in population growth, urbanization and migration due to transition in urban household growth and income distribution. The total retail market in the top 67 cities in India in 2006 was Rs. 2.55 trillion, which is expected to increase to Rs. 3.91 trillion in 2011. According to CRISIL, around 87 percent of the retail opportunity comes from top 25 cities compromising Metro Delhi, Mumbai, Calcutta, Mini Metros Hyderabad, Chennai, Bangalore, Mini Metros Ahmedabad and Pune, Tier I cities of Kanpur , Nagpur, Surat and Ludhiana, Tier II cities Coimbatore, Chandigarh, Lucknow, Kochi, Jaipur and Tier III cities Vadodara, Vizag, Indore, Vijaywada, Thiruvananthpuram, Bhopal, Nashik and Madurai. The levels of penetration in the top 67 cities are expected to leap. Organized retail has been established in Metros and Tier 1 cities, other cities having negligible level of penetration Retail Formats in India: Conventional Formats Kirana These are food and non-food neighborhood counter stores, also called ‘mom and pop stores’ in western countries. These are big chunks forming the segregated and unorganised retail segment. These are family-ownedand- run retail-outlets picking the goods from wholesalers totaling to around 12 million stores across India. Mandis These are the largest chunk of unorganised retail catering to urban and rural masses. Mandis are physically located at different regions to enhance convenient shopping. The sellers bring across various products like eatables,vegetables and fruits, pulses, cereals, spices etc. The most prominent of them are sabzi mandis found in most of the localities across India. Village Haats This form is operating in rural areas where buyers and sellers gather once in a week or month from nearby villages and small towns to cater their livelihood and leisure needs. These haats are a source of entertainment and socialization among rural masses. Push Cart Vendors The are categories of vendors roaming from door to door in various localities selling fruits, vegetables, and other eatables, from which mostly housewives makes purchases that too on credit. Modern organized retail formats: Shopping malls Area -60000-700000 square feet Point of differentiation: Multi format, Multi products, Multi brand caterings, Lifestyle needs. Hyper market Area: 50000 – 100000 square feet Point of differentiation: Multi vertical Super markets Area: 5000-10000 square feet. Point of differentiation: low cost, low margin high volume, self service operations design to serve total need for food, laundry household maintenance products. Departmental stores Area: 20000-30000 square feet. Point of differentiation: single vertical , several product lines Apparels store Area: 20000-25000 square feet Point of differentiation: Multi branded, Single vertical, focusing on high consumers Specialty stores Area:-2000-5000 square feet Point of differentiation: Narrow product line with deep assortment ,multi branded, Single vertical on specific needs of the customers. Exclusive formats Area: 500-5000 square feet Point of differentiation: Owned/Franchised, Single products 8. Convenience stores Area: 200-500 square feet Point of differentiation: Located near residential area, open long hours, seven days in a week, limited product line, high turnover Advantages of conventional Modern Organized retail formats Conventional formats: Low operating cost Overheads. Proximity to consumers. Low operating hours. Strong relations with customers. Modern organized retail formats: Large bargaining power with suppliers. Range variety of goods. Quality assurance( Brand related, durability) Convenience Hygiene Business Models suiting Indian Scenario Cash--carry Wholesale Model Cash--carry is a form of retail trade in which goods are sold from a wholesale warehouse operated either on a self-service basis where customers settle the invoice on-the-spot or pay cash and carry the goods away themselves. The cash--carry player also performs many value-added functions, including selling and promoting, buying and assortment building, bulk-breaking, warehousing, transporting, financing, risk-bearing, supplying market information, and providing management services. Hub-and-spoke Model Retail Chains are entering residential areas with the hub-andspoke model, whereby one large store supports various smaller stores in the nearby residential areas. This is win-win model is well-suited to the Indian business scene where large stores obtain supplies from the warehouse and supplies to the consumers, involving both large payers acting as wholesalers and local kiranas as retail outlets. With efficient supply chain management, availability of space and proper technology in place, this will not take much time. The Piramyd Retail’s Trumart Stores (food and grocery) in Mumbai and Pune are based on a similar model. Growth Enabling Factors Higher Disposable Income The disposable income has been showing a rapid increase from the last few years and is expected to grow steadily because the proportion of the major consuming class (population having incomes higher than Rs 90,000) is expected to reach 48 percent by 2009-10 from 20 percent in 1995-95, at the 2001-02 prices, at a CAGR of 9.3 percent over the next 8 years leading to new consumption patterns due to increasing depth in the consumers’ pocket. Growing Working women population The propensity to spend in the case of working women is higher by 1.3 times as compared by housewives. According to the census report, the population of working women increased to 26 percent in 2001 as compared to 22 percent in 1991. Adoption of Nuclear Family culture The increase in per capita income paved way to increase the nuclear-family culture. The proportion of nuclear families as a percentage of total household population has increased as shown by fall in average household size from 5.57 in 1991to 5.36 in 2007, expected to fall further to 5.02 by 2011. This will fuel the growth of organised retail. Baby Boomer Effect The demographics of Indian population has a steep growth in earning population (15-60 yrs). In 2000, 593 million people (58.3 percent of total population) constituted the age bracket of 15-60 yrs – growing from an unprecedented level of 335 million people (54 percent of total population) in 1975 at a rate of 77 percent (CAGR of 2.3 percent) in contrast to a population growth of 64 percent (CAGR of 2 percent) over the same period of 25 years. Over the next 15 years, the earning population is expected to increase to 62.8 percent in 2015, translating into a population of 782 million. Growth in Urban Population Urbanization has increased at a rate of 2.7 percent over the last 10 years (1990-2000). In 2000, the urban population was estimated to be 281 million (27.7 percent of the total population). This trend is likely to continue and urbanization is expected to grow at 2.4 percent between 2000 and 2015. In 2015 the urban population is expected to be 401 million, constituting 32.2 percent of the total population. Robust Outlook towards Branded products Due to liberalization of manufacturing sector, various organized branded products have entered into Indian markets, thereby developing and widening the basket for branded finished goods. With the advent of International competition, new trends and lifestyles are evolving among India masses resulting into 10-15 percent growth in branded products. This has established the base for organized retail market in India. Growth in Retail Malls and various other new Formats Real Estate players like Raheja’s, Future Group, DLF, Omaxe, Piramal Group, Parsvnath, Unitech are developing retail malls and leasing out the retail spaces to various retailers of varied products making it a one-stop shopping destinations in urban and semi-urban cities. These shopping-cum-entertainment malls are wooing young buyers to increase their conversion rate backed by increasing foot-falls. Around 358 malls have come up by 2007, covering a total space of 87 million square feet, thereby pushing organised retail to new heights. Plastic Money becoming a greater Pie of credit The use of plastic money in the form of debit and credit cards has expanded multifold in last 5 years. The number of credit cards has grown at a CAGR of 28 percent and debit cards galloped by 140 percent. The customers have adopted the habit of electronic payments and leveraging their pockets shifting from basic needs to lifestyle products. Swot Analysis of Organized Stores Strength: As being technology intensive .these stores are able to forecast customer demand, shorten lead time reduce inventory holding ultimately save cost. Wide assortment show customer has variety of choice Weakness: Despite of high footfall the conversion rate is very low. As a result retail measure experiencing an ROI of only 8% to 10% Organized stores have less customer loyalty as compare to unorganized stores. Low customer knowledge Lack of personal touch Opportunities: Indian middle class is already 30 crores projected to grow to over 60 crores by 2010 making India one of the largest consumer markets in the world. According to KSA projections by 2015 India will have 55 crores people under the age of 20 reflecting the enormous opportunities possible in the kids teens retailing segments. Threats: High real estate rent. Poor Infrastructure Less develop shopping culture. Due to fragmented market high distribution cost. Swot Analysis of Unorganized Stores Strength: Located in prime residential area. Rental for large stores in these area are generally not available. They enjoy a near monopoly in area that is backward or do not have a population with sustainable purchasing power like rural areas. since organized retailer are unlikely to enter such reasons Weakness: Do not provide quality assurance. Less concern about ambience hygiene issue. Opportunities: Low capital requirements Proximity to consumers and strong relationship help them to gauge .Customer needs stock accordingly thus gaining more business. Threats: Increase in use of credit cards With huge stores coming up in catchments areas of 5-7 km of approachable distance larges chains planning to set up hub spoke, smaller stores. So the very existence of traditional store is in danger. Low or no bargaining power due to small scale of operations Due to smaller in size unable to stock a variety of goods. Provide not many options to the customers. Why Indian consumers want more experiential shopping today? The Indian consumer is changing rapidly. The average consumer today is richer, younger and more aspirational in his or her needs than ever before. Consumers now value convenience and choice on a par with getting value for their hard-earned money. A range of modern retailers is attempting to serve the needs of the ‘new’ Indian consumer. Today Indian consumers want not only buying but a full shopping experience. For this one of the important factors responsible is change in life style as well as disposable income. As per Indian consumer’s map , approximately 209 million of total household in India 6 millions are rich having annual income of more than US$ 4700 .this number were 1 million household in 1994 and 3 million households in 1999-00 thus this class is growing very rapidly. About 50% of these families are living in metros and spending more than eighteen billion annually. As per the need of these families around 62% market for premium products is concentrated in Mumbai, Bangalore, Chennai and Kolkata. But now retail market is moving toward big and also small cities . India’s 8.5% of the retail market concentrated in 8 big cities .As per an estimate among rich class top most 1 million customers comes under superrich category growing by 20% per annum and shows behavior similar to international consumers . While this segment is worth targeting for high-end premium products, it is not the key driver of the organized retail sector. The real driver of the Indian retail sector is the bottom 80% of the first layer and the upper half of the second layer of the income map (see ‘Map of India’s income classes’ below). This segment of about 40 million households earns USD 4,000-10,000 per household and comprises salaried employees and self-employed professionals. This segment is expected to grow to 65 million households by 2010 and is currently the key driver behind explosive growth in passenger car sales (USD 5 billion in 2004) and mobile phone penetration (over 70 million). The top 6 Indian cities -Mumbai, Delhi, Chennai, Kolkata, Bangalore and Hyderabad -are the darlings of India’s exploding economy. They represent 6% of the population, but contribute 14% of India’s GDP. They are the centers of business, finance, politics and the emerging sunrise industries such as IT, pharma and ITeS, which have put India on the global map. These cities are also the barometer of India’s economic development and most foreign investors have flocked here. Are Indian consumers are ready for organize retail? By the end of 20th century in Indian retail sector too many significant changes has taken place. The retailing industry, which in early1990s was dominated by the unorganized sector, is now going a drastic change with a rapid growth in the organized sector with the entry of many corporate groups such as Tata, RPG, ITC and Bennett Coleman Company. Now Indian consumers are much aware about domestic and foreign products by the different source of media, such as newspaper ,television and the internet Apart from this there are too many social changes like increase in working couples , increase in number of nuclear families , rapid Urbanization.goverment policies ,increase in availability of retail space , increase in disposable income , availability of educated manpower also catalyzed the growth of organize retail . Food retailing was the most important area where players like food worlds establishing their outlets all over the India. Beside it supermarket and departmental stores now replacing traditional grocery stores all over the India , by the entry of fast foods (McDonalds), packaged foods (MTR), vending machines and specialty beverage parlors (Nescafe, Tata Tea, Cafe Coffee and Barista) brought about significant changes in the eating habits of Indian consumers. Literature Review Indian retail sector still has long way to go till now many research work and articles have been return over Indian retail. These articles and research work mainly focus upon huge untapped markets in Indian retail. They mainly talk about the opportunities available in the Indian market for the growth of organized retail. Some of the important research paper and articles which inspired me and catalyzed my thinking process over this topic are: â€Å"The evolving retail market in India† was written by Dale Anne Raiss and Ranjan biswas working as partner and head of market at Ernst Young .In this report they talk about largely untapped potential in retailing in India. They also tal